The reduction of a redox-active ligand is shown to drive reversible switching of a Cu(I) [2]pseudorotaxane ([2]PR(+)) into the reduced [3]pseudorotaxane ([3]PR(+)) by a bimolecular mechanism. The unreduced pseudorotaxanes [2]PR(+) and [3]PR(2+) are initially self-assembled from the binucleating ligand, 3,6-bis(5-methyl-2-pyridine)-1,2,4,5-tetrazine (Me(2)BPTZ), and a preformed copper-macrocycle...

A dimeric PR-1-type pathogenesis-related protein (PR-1-5), recently identified in wheat, was found to interact with Stagonospora nodorum ToxA in both yeast two-hybrid and co-immunoprecipitation assays. Site-specific mutational analyses revealed that the RGD motif of ToxA is not targeted by PR-1-5, whereas two surface-exposed asparagine residues are essential for the interaction: the N102 residu...

Background: Pityriasis rosea (PR) is a common papulosquamousskin disorder that is suspected to have an infectious etiology.We aimed to study the role of human herpesvirus-6 (HHV-6) inthe pathogenesis of PR.Method: We used immunohistochemical (IHC) assays to detectHHV-6 in patients with PR. Fifty-one patients with PR and 35 ageand sex matched healthy control samples were enrolled in thestudy. Th...

dear editor-in-chief   lesional histopathological features in pityriasis rosea (pr) are non-specific (1).  our aim here is to investigate whether a histopathological take-off sign (tos) is associated with pr.

PROOF. It suffices, by standard facts about probability measure, to prove the claim for cylinders C(w′) ⊆ ′, where w′ = w0, . . . wk. We use induction on k. The base case (k = 0) follows from Lemma 7. Namely, C( ) = ′, and ρ−1( ′) = \ ρ−1( ). Thus Pr (ρ−1( ′)) = 1 − Pr (ρ−1( )) = 1. For the induction step, suppose that the claim holds for the prefix w′ = w0w1 . . . wk. Let D[w′] = ρ−1(C(w′)). D...

1 pi − 2 j+1 > 7pr − 4pr > pr . If r is odd, set nk = ∏r1 pi − 2k+1. Then nk ≡ 3(4) (since 32 ≡ 1(4)). But no pi divides nk for 1 ≤ i ≤ r , so the integer nk has some prime factor qk ≡ 3(4) with qk > pr . If j = k, say j > k, the assumption that qk also divides n j leads to the same contradiction as earlier: since nk − n j = 2 j+1 − 2k+1 = 2k+1(2 j−k − 1), we have qk | 2 j−k − 1 and hence qk < ...

Four new Pr(III) mononuclear complexes of formula [Pr(ntfa)3(MeOH)2] (1), [Pr(ntfa)3(bipy)2] (2), [Pr(ntfa)3(4,4?-Mt2bipy)] (3) and [Pr(ntfa)3(5,5?-Me2bipy)] (4), where ntfa = 4,4,4-trifuoro-1-(naphthalen-2-yl)butane-1,3-dionato(1-), 5,5?-Me2bipy 5,5?-dimethyl-2,2?-dipyridine, 4,4?-Mt2bipy 4,4?-dimethoxy-2,2?-dipyridine, have been synthesized structurally characterized. The display the coordina...