A detailed theoretical investigation of the charge transport mechanism in poly(4-vinyl-imidazole) (P4VI), the parent polymer of a series of N-heterocyclic-based membranes used as an electrolyte in proton exchange membrane fuel cells, is presented. In particular, Density Functional Theory (DFT) results obtained for small model systems (protonated imidazole dimers and trimers) suggest that the co...

The cathode/electrolyte LSCF48/YDC15 couple is a building block of a new innovative and competitive design of a high temperature fuel cell, operating in the range between 600 and 700°C. It is based on the idea for a junction between a proton conducting SOFC (PCFC) anode/electrolyte part and a SOFC cathode/electrolyte part through a mixed H and O conducting porous ceramic membrane. Thus, in this...

objective(s): investigation of acute effect on cellular bioenergetics provides the opportunity to characterize the possible adverse effects of drugs more comprehensively. this study aimed to investigate the changes in biochemical and biophysical properties of heart mitochondria induced by captopril and nifedipine antihypertensive treatment. materials and methods: male, 12-week-old wistar rats i...

in the current work, graphene oxide (go) samples were prepared at room temperature from graphite flakes using a modified hummer's method to produce metal-free electrocatalysts. the effect of the duration of the oxidation process on the structural, chemical and physical characteristics of the go samples was evaluated using x-ray diffraction (xrd), fourier transform infrared spectroscopy (ftir), ...

We are proposing a conceptual membrane electrode assembly (MEA) of proton exchange water electrolyzer that includes layer graphene oxide (GO) at the cathode side. This GO primarily reinforces MEA to allow operation higher pressure difference between and anode Additional benefits would be perfect prevent both hydrogen crossover thus for pure, dry escaping directly from without losses due crossov...

A “water free,” proton conducting membrane for use in a fuel cell is fabricated as a highly conducting sheet of converted solid state organic amine salt, such as converted acid salt of triethylenediamine with two quaternized tertiary nitrogen atoms, combined with a nanoparticulate oxide and a stable binder combined with the converted solid state organic amine salt to form a polymeric electrolyt...

Water management is one issue that must be surpassed to ensure high membrane proton conductivity and adequate reactant transport in the membrane-electrode assembly (MEA) simultaneously. A well-designed water system based on a comprehensive understanding of inner part polymer electrolyte (PEM) fuel cell. In this work, phenomena MEA PEM cell are analyzed by using mathematical model. The diluted s...

Of course not! Humankind has cleared a lot of survival tests before reaching this point in time and shall smartly find out new ways to evolve through these hard times too. As a solution to the world energy and environmental crisis, scientists with foresight have been developing hydrogen based clean power generators: The Fuel Cells. Fuel cells are electrochemical devices which convert chemical e...

Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...

Density functional theory calculations are used to investigate the energetics of protons crossing triple phase boundaries based on a metal catalyst, Pd or Ni, and barium zirconate. Our calculations show that the proton transfer reaction at these interfaces is controlled by the terminal layer of the electrolyte in contact with the metallic and gas phases. The hydrogen spilling process onto the e...