The complexity of biological networks motivates the use of computer or ”in silico” stochastic event based modeling approach to better identify the dynamic interactions of different processes in the cell. This requires the computation of the time taken by different processes in the cell on a per molecule basis. We present a mathematical formulation for the estimation of the reaction time between...

Experiments on the diffusion-limited corrosion of porous copper clusters in thin gap cells containing cupric chloride are reported. By carefully comparing corrosion front velocities and concentration profiles obtained by phase-shift interferometry with theoretical predictions, it is demonstrated that this process is well-described by a one-dimensional mean-field model for the generic reaction A...

Robustness against the presence of environmental disruptions can be observed in many systems chemical reaction network. However, identifying underlying components a system that give rise to robustness is often elusive. The influential work Shinar and Feinberg established simple yet subtle network-based conditions for absolute concentration (ACR), phenomenon which species mass-action has same an...

Saccharin is a powerfully sweet nonnutritive sweetener that has been approved for food-processing applications within the range of 100-1200 mg/kg. A simple, rapid, and cost-effective sequential injection analysis (SIA) technique was developed to determine the saccharin level. This method is based on the reaction of saccharin with p-chloranil in an ethanol medium with a hydrogen peroxide (H₂O₂) ...

the determination of the optimal distribution of the catalytic activity profile, whichmaximizes the catalytic effectiveness, in created unsteady state conditions, is analyzed andtreated numerically for the case of a simple reaction. it was proven that the modulation, of thetemperature and the reactant concentration of the external bulk fluid, leads to a considerableincrease of the catalytic eff...

In Microbial Fuel Cells (MFCs), a mass transfer impact might be larger than expected because it not only effects the mass transfer losses (substrate flux [1, 2] and removal of waste [2]), but also effects the activation losses (mediator [3-5]) and the ohmic losses (proton transfer [6]). However, the convection/diffusion of the reactant transport from the bulk (reactant transport), which can be ...

Copper sulfide nanotubes and nanoparticles have been successfully synthesized by a hydrothermal process at 160 °C for 10 h, employing copper chloride (CuCl2·2H2O) and thioacetamide as starting materials, polyethylene glycol 400 as surfactant. The products are characterized by X-ray power diffraction, scanning electron microscopy, UV–vis spectroscopy and fluorescence spectroscopy, respectively. ...

Nanocrystalline SnOx particles (x 0–2) were synthesized using tetramethyltin (Sn(CH3)4) vapor as the particle precursor reactant in hydrogen/oxygen/argon (H2/O2/Ar) flames. The particle composition and morphology were characterized using X-ray diffractometry, transmission electron microscopy, and nitrogen (N2) surface adsorption. By controlling the concentration of oxygen in the reactant gases ...

We use molecular dynamics simulations at the atomistic level to build a model of aromatic polyamide polymer used in reverse osmosis membranes, from mixture m-phenylene diamine (MPD) and trimesoyl chloride monomers (TMC). Our purpose is different MPD TMC ratios reproduce compositional depth-dependence observed experimentally during interfacial polymerization. range 1:4 5:1 have been employed. Re...

A mathematical model for the startup period of a fixed-bed reactor with first-order reaction kinetics, axial dispersion and film mass transfer resistance was formulated and solved analytically using Laplace transform. The solution can be used to correlate or predict the reactant concentration profiles in the effluent of the reactor. The effects of both the Peclet number and Biot number on the e...