Solid-state properties of piroxicam benzoate, an ester prodrug of piroxicam, were investigated. Samples were prepared by recrystallization from various organic solvents (toluene, ethanol, methanol, ethyl acetate and acetone). Recrystallized samples were characterized by means of FTIR, DSC, TGA, SEM and XRPD. DSC, TGA and XRPD methods confirmed that piroxicam benzoate crystallized in two pseudop...

The interaction of calcite with trivalent europium under recrystallization conditions was studied on the molecular level using site-selective time-resolved laser fluorescence spectroscopy (TRLFS). We conducted batch studies with a reaction time from seven days up to three years with three calcite powders, which differed in their specific surface area, recrystallization rates and impurities cont...

The catalyzing effect on nucleation of recrystallization from existing grains resulting from previous lower temperature deformation is analyzed, analogous to the size effect of foreign nucleus in heterogeneous nucleation. Analytical formulation of the effective nucleation site for recrystallization leads to a negative temperature dependence of recrystallized grain size of metals. Non-isochronal...

strain induced precipitation in hsla-100 steel was investigated by conducting hotcompression and relaxation tests at temperature range of 850°c to 1100°c and strain rate of 0.001s-1 to 1s-1. the absence of dynamic recrystallization at temperatures below 1000°c was attributedto the influence of dynamic precipitation. the stress relaxation tests showed that strain inducedprecipitation is possible...

lactide was synthesized by reverse polymerization of low molecular weight poly(lactic acid) with two different molecular weights:1500 and 2500. two different lactide purification processes such as: recrystallization in ethyl acetate and washing the crude lactide with ether before recrystallization in ethyl acetate were evaluated. it has been demonstrated that increasing the molecular weight of ...

Isothermal interrupted hot compression tests of 5754 aluminum were conducted on a Gleeble-3500 thermo-mechanical simulator at temperatures of 350 °C and 450 °C, and strain rates of 0.1 s−1 and 1 s−1. To investigate the metadynamic recrystallization behavior, a range of inter-pass delay times (5–60 s) was employed. These tests simulated flat rolling to investigate how softening behaviors respond...

Since its invention by Goss in 1934, grain-oriented (GO) electrical steel has been widely used as a core material in transformers. GO exhibits a grain size of over several millimeters attained by secondary recrystallization during high-temperature final batch annealing. In addition to the unusually large grain size, the crystal direction in the rolling direction is aligned with <001>, which is ...

the effects of carbon content on the dynamic and static softening mechanisms of ti microalloy steels were investigated both in ferrite and austenite regions. the results obtained showed that recrystallization rate decreased as the percentage of carbon content was increased from 0.0035 to 0.110. this is due to the ti(cn) and tic precipitates and also the free carbon content. in the ferrite regio...

We herein present a top-down methodology to prepare nanosized zeolites with tunable size by combining post-synthesis milling and fast recrystallization of several minutes (10 min for SSZ-13 and 5 min for AlPO4-5). A continuous-flow recrystallization process is demonstrated to further enhance the overall product efficiency.

The deformation and recrystallization mechanisms which control the viscoplasticity of ice from polar ice sheets have been investigated. The high plastic anisotropy of ice crystals is responsible for the development of a non uniform internal stress field within the polycrystal. Strain-shadows produced by sub-grain are observed in polarized light when the rotation recrystallization regime is domi...