Part A I. General methods S1-S2 II. Synthesis of boronate esters (Table 1) S3-S6 III. Competition studies (Table 1) S7 IV. Synthesis of haloboronate esters (Scheme 1) S8-S13 V. Selective Suzuki-Miyaura coupling with haloboronate esters (Table 2) S14-S18 VI. Deprotection of boronate esters (Table 2) S19-S22 VII. Total synthesis of ratanhine (Scheme 3) S23-S39 Part B VIII. NMR spectra Part C IX. ...

Table of Contents General methods S1 Reagents and materials S2 General protocol for the preparation of starting chiral ynamides S3 General procedures for the allylation of stereodefined trisubstituted copper enolate S5 Optimization reactions S8 Products of the enantioselective allylic alkylation reaction S9 Cleavage of oxazolidinone moiety 4 S19 References S21 X-Ray crystallographic analysis da...

Hybrid incompatibility plays an important role in establishment of post-zygotic reproductive isolation. To unveil genetic basis of hybrid incompatibilities between diverged species of genus Oryza AA genome species, we conducted genetic dissection of hybrid sterility loci, S22(t), which had been identified in backcross progeny derived from Oryza sativa ssp. japonica (recurrent parent) and South ...

The VV10 and rVV10 nonlocal correlation functionals are consistently implemented and assessed, with the goal of determining if the rVV10 nonlocal correlation functional can replace the VV10 nonlocal correlation functional in the recently developed B97M-V density functional, to give the B97M-rV density functional. Along the way, four density functionals are simultaneously tested: VV10, rVV10, B9...

Objectives: The purpose of this study is to reduce fabric consumption by improving marker efficiency. improvements the existing markers lead wastage during cutting process. Methods: Gerber CAD/CAM software version AccuMark 8.5.1 used in present was made pattern and marker. A noble approach conduct experiment through software. Easy produced at initial stage then it replaces actual market conside...

Synthesis S1 S1.1 Context S1 S1.2 Mass Rapid Transit S2 S1.3 MRT Impacts on Policy Objectives S7 S1.4 Issues in Project Development S11 S1.5 Applicability of the MRT Options S22 S1.6 Research Requirements S26 Synthesis 1 S1.1 Context 1 S1.2 Mass Rapid Transit 2 S1.3 MRT Impacts on Policy Objectives 7 S1.4 Issues in Project Development 11 S1.5 Applicability of the MRT Options 22 S1.6 Research Re...

Abstract: A CMOS LNA using MEMS Technology. Highlighting the "on-chip" inductors with quality factor used to replace previous off chip models. The operating frequency fo=2.4GHz with power dissipation of 20mW and overall noise figure of less than 1dB . It achieves an input return loss S11=-37.7dB. With a supply voltage of Vdd=2.7V giving out S21=24.3dB, S12= 40.7dB, and S22=-30dB. Cascode topolo...