As kerogen is the main organic component in shale, the adsorption capacity, diffusion and permeability of the gas in kerogen plays an important role in shale gas production. Based on the molecular model of type II kerogen, an organic nanoporous structure was established. The Grand Canonical Monte Carlo (GCMC) and Molecular Dynamics (MD) methods were used to study the adsorption and diffusion ca...

We analyze the gas separation performance of five polyether-block-amide type copolymers (Pebax® 1657, Renew®, 2533, 3533 and 4533). These codes are composed different hard rubbery segments with proportions. Dense membranes were prepared by casting-solution method studied elemental, thermogravimetric X-ray diffraction analyses, FTIR-ATR spectroscopy single mixed permeation. Codes best those poly...

Graphene oxide (GO) membranes have shown promising gas separation characteristics that make them of interest for large-scale industrial applications. However, the gas transport mechanism for GO membranes is unclear due to inconsistent permeation and separation results reported in literature. GO membranes examined for gas separation were prepared on substrates and/or by synthesis methods that ar...

This work continues the development of a numerical model to simulate transient tritium transport on breeder zone (BZ) level for EU helium-cooled pebble bed (HCPB) concept DEMO. The basis is open-source field operation and manipulation framework, OpenFOAM. key output quantities are concentration in purge gas coolant inventory inside BZ structure. New features briefly summarized. As first relevan...

The novel concept of a microfluidic chip with an integrated three-dimensional fractal geometry with nanopores, acting as a gas transport membrane, is presented. The method of engineering the 3D fractal structure is based on a combination of anisotropic etching of silicon and corner lithography. The permeation of oxygen and carbon dioxide through the fractal membrane is measured and validated th...

The gas permeability of α-alumina, yttria-stabilized zirconia (YSZ), and silicon carbide porous ceramics toward H₂, CO₂, and H₂-CO₂ mixtures were investigated at room temperature. The permeation of H₂ and CO₂ single gases occurred above a critical pressure gradient, which was smaller for H₂ gas than for CO₂ gas. When the Knudsen number (λ/r ratio, λ: molecular mean free path, r: pore radius) of...

The multi-walled carbon nanotube (MWCNT) dispersed polymethylmethacrylate (PMMA) composite membranes have been prepared for hydrogen gas permeation application. Composite membranes are characterized by Raman spectroscopy, optical microscopy, X-ray diffraction, electrical measurements and gas permeability measurements. The effect of electric field alignment of MWCNT in PMMA matrix on gas permeat...

Gas separation only became a major industrial application of membrane technology in the past 30 years, but the study of gas permeation through membranes has a long history. Systematic studies began with Thomas Graham who, over a period of 20 years, measured the permeation rates of all the gases then known, through every diaphragm available to him [1]. This was no small task because his experime...

Poly (ether-block-amide) /poly (ethylene glycol)/ carbon nanotubes mixed matrix membranes have been successfully fabricated using solvent evaporation method to determine the effect of ethylene oxide groups on the performance of produced membranes. The effects of CNTs (2-8 wt%) and PEG (up to 50 wt%)were investigated in both single and mixed gas test setup in different temperature and pressure. ...

A gas permeation model (Coupling Model) has been developed which has the flexibility to be used for different membrane module configurations. The aim of this work is to predict the performance of a single stage gas separation process using membranes and provide a comprehensive description of process parameters like flow rates, composition, stage cut and stream pressure. The significant feature ...