In this paper a concise, efficient, and environmentally benign method for the synthesis of 3-alkoxymethylcoumarin is described. From the reaction of 3-cyanochromene with an alkoxide and arylamine in THF, (Z)-2-phenylimino-3-alkoxymethylchromene was obtained as a novel intermediate via an isomerization of the double bond, a 1,2-addition of alkoxide, a Michael-type addition of aniline, an another...

the aim of this work is to synthesize and investigate the performance of yttria-doped zirconia solgelcoatings in the chemical corrosion prevention of zircaloy-4 (zirconium alloy) in a 1 n h2so4environment. the influence of four different molar ratios of water to alkoxide, namely 1, 4, 12, and20, on the coating quality and its corrosion prevention performance was investigated. differentialtherma...

A general introduction to the application of zirconia materials is provided in this chapter with a specific emphasis on the application in membrane and the use of zirconia as a high-k material. The main focus of this thesis is the preparation of suitable heteroleptic alkoxide precursors for the application in sol-gel and metalorganic chemical vapor deposition (MOCVD). Selecting suitable alkoxid...

Abstract:Nanostructured titania was synthesized by colloidal and polymeric sol-gel routes. Stable colloidal and polymeric titania sols were prepared by adjusting the proper values of the acid/alkoxide and the water/alkoxide molar ratios. The properties of sols were determined by dynamic light scattering technique and synthesized titania was characterized by thermogravimetry and differential the...

The feasibility of gas phase deposition using a Ti alkoxide precursor for precise surface modification catalysts was demonstrated by modifying mesoporous alumina support with oxide overcoat.

The synthesis of magnesium and zinc complexes of bidentate anionic alkoxide ligands with saturated-backbone carbene groups is reported. Mono(ligand) and bis(ligand) complexes [M(L(R))N''](2) and [M(L(R))(2)] (M = Mg, Zn, N'' = N(SiMe(3))(2), L(R) = [OCMe(2)CH(2){CNCH(2)CH(2)NR}] R = (i)Pr, Mes, Dipp) have been isolated, and some structurally characterised and compared with the new unsaturated c...

Fluoride-free cross-coupling of aryl- and alkenyldimethylsilanes with organic halides proceeded in the presence of monocopper(I) alkoxide of ethylene glycol.

1,6-Enynes can be transformed into vinylidenecyclopentanes via gold-promoted 5-exo dig cyclisation followed by 1,5-hydride or -alkoxide shift.

A general and convenient method for the stereoand regiospecific synthesis of conjugated alkadienes, alkenynes, arylated alkenes, and other olefinic compounds is described. The reaction of (E)or (Z)-lalkenyldisiamylboranes, or 2-(E)-l-alkenyl-l ,3,2-benzodioxaboroles easily obtainable by hydroboration, with either (E)or (Z)-l-alkenyl halides in the presence of a catalytic amount of tetrakis(trip...