Infrared multiple photon dissociation spectra for the smallest atmospherically relevant anions of sulfuric and nitric acid allow us to characterize structures and distinguish between clusters with a bisulfate or a nitrate core. We find that bisulfate is the main charge carrier for HSO(4)(-)·H(2)SO(4)·HNO(3) but not for NO(3)(-)·H(2)SO(4)·HNO(3). For the mixed dimer anion, we find evidence for t...

Though ammonium bisulfate is one of the most common of atmospheric hygroscopic aerosols, knowledge of its interaction with water has, until now, been extremely limited. This paper presents our observations on single isolated ammonium bisulfate aerosol particles, as they interact with water vapor at temperatures ranging from -40 to 30 °C. The complete phase diagram in the temperature/composition...

Selective low temperature conversion of methane to methanol remains as a grand challenge for chemical technology. The top five highest yielding systems utilize Pt, Hg, Au, I, and Pd catalysts and a concentrated sulfuric acid reaction medium (acetic acid in the case of Pd). The most promising system to date uses Pt(bpym)Cl2 as the catalyst and concentrated H2SO4 as both the solvent and the oxida...

Epidermal growth factor (EGF), a multifunctional growth factor, is a regulator in a wide variety of physiological processes. EGF plays an important role in the regulation of liver regeneration. This study was aimed at investigating the methylation level of EGF gene throughout liver regeneration. DNA of liver tissue from control rats and partial hepatectomy (PH) rats at 10 time points was extrac...

Cellulose acetate (CA) was successfully synthesized by the acetylation of TCF cellulose pulp from oil palm empty fruit bunches (OPEFB) at room temperature, using acetic anhydride as the acetylating agent and acetic acid as the solvent in the presence of sulfuric acid/sodium bisulfate as catalysts. Degree of substitution (DS) was controlled by the variables of acetylation time and acetic anhydri...

The distribution of charged species produced by electrospray of an ammonium sulfate solution in both positive and negative polarities is examined using Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). Positively-charged ammonium bisulfate cluster composition differs significantly from negatively-charged cluster composition. For positively-charged clusters all sulfuric acid...

Transdermal drug delivery is an alternative route for systemic drug delivery which minimizes the absorption and increases the bioavailability. Orally Clopidogrel bisulfate has a short elimination half-life (7-8 hrs.), low oral bioavailability (50%) undergoes extensive first pass metabolism (85%) and frequent high doses (75 mg) are required to maintain the therapeutic level as a result, dose dev...