Single crystals of the title compound, Na(H2AsO4), were obtained by partial neutralization of arsenic acid with sodium hydroxide in aqueous solution. The crystal structure of Na(H2AsO4) is isotypic with the phosphate analogue and the asymmetric unit consists of two sodium cations and two tetra-hedral H2AsO4- anions. Each of the sodium cations is surrounded by six O atoms of five H2AsO4- groups,...

Titrimetric estimation of calcium with disodium ethylene diamine tetra-acetate (E.D.T.A., sodium edetate), as performed on serum (Baron and Bell, 1957), cannot be applied directly to most other biological specimens because of their high concentration of phosphate. A high ratio of phosphate to calcium in the material titrated causes a drawnout and inaccurate endpoint. A rapid procedure for calci...

The title compound, C9H10N4O, was obtained unintentionally by hydrolysis of 4-amino-1-benzyl-5-methyl-sulfanyl-1,2,4-triazolium tetra-fluoro-borate in the presence of sodium azide. In the crystal, alternating layers of polar amino-triazolinone and apolar benzene moieties are observed. N-H⋯O hydrogen bonds between the amino and carbonyl groups form infinite chains along [010]. These infinite cha...

The structure of triclinic disodium hafnium disilicate, Na2HfSi2O7, has been determined by laboratory powder X-ray diffraction and refined by the Rietveld refinement. The structure is a framework made of alternate layers of HfO6 octa-hedra and SiO4 tetra-hedra linked by common O atoms. Sodium atoms are located in the voids of the framework, aligned into tunnels along the [010] direction. Na2HfS...

In the title compound, [FePdCl(C5H5)(C8H11N)(C18H15Sb)], obtained by reaction of diphen-yl(N,N-di-methyl-amino-methyl-ferrocen-yl)stibine with sodium tetra-chlorido-palladate(II) in acetone, the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by a C atom of the ferrocenyl ring, and by N, Cl and Sb atoms. The Sb and N atoms are trans to each other.

Biochemicals 5-hydroxytrptophan, 5-hydroxy indole acetic acid, ketanserin, bicuculline, baclofen, atropine, sodium octyl sulfonic acid, ethylene diamine tetra acetic acidEDTA, D-glucose, calcium chloride, bovine serum albumin fraction V, Superoxide dismutase from bovine erythrocytes were purchased from Sigma Chemical Co., St. Louis, USA. All other reagents were of analytical grade purchased loc...

The title compound sodium dysprosium(III) bis-[tungs-tate(VI)], NaDy(WO(4))(2), has been synthesized under high temperature solution growth (HTSG) conditions in air. The compound crystallizes with the scheelite structure and is composed of isolated WO(4) tetra-hedra ( symmetry) with one set of bond lengths and distorted [(Na/Dy)O(8)] dodeca-hedra ( symmetry; occupancy ratio Na:Dy = 1:1) with tw...

Explorations of the A(1+)-RE(3+)-Mo(6+)-O(2-) (A(1+) is an alkali metal cation, RE(3+) is a rare-earth metal cation) quaternary systems prepared by the high-temperature solution growth method led to the title structure, sodium erbium bis-(molyb-date), NaEr(MoO(4))(2). It is isostructural to the scheelite structure (CaWO(4)) and is composed of [MoO(4)](2-) tetra-hedra with symmetry and [(Na/Er)O...

The title compound, sodium potassium trialuminium tetra-kis-(orthoarsenate), was prepared by solid-state reactions. The anionic framework consists of corrugated layers parallel to (010) and is made up of corner-sharing AlO6 octa-hedra (site symmetries .2. and 2/m..) that are connected to isolated AsO4 tetra-hedra (site symmetries .2. and m..) through edge- and corner-sharing. The alkali cations...

The new phase potassium penta-sodium trimanganese hexa-kis(molybdate), KNa5Mn3Mo6O24, has been synthesized using solid-state methods. The structure is composed of M 2O10 (M = Mn, Na) dimers and MoO4 tetra-hedra (point group symmetry 2) sharing corners and forming layers parallel to (100), which are linked via common corners of another type of MO4 tetra-hedra, forming a three-dimensional structu...