Solid Oxide Fuel Cells (SOFCs) can convert chemical energy into electrical energy, with high conversion rate, safe operation, no pollutant emissions, and is one of the most potential new power generation devices in future. However, at low medium temperature (below 800℃), cathode impedance SOFCs will increase sharply, resulting adverse effects on cell performance. Finding materials that work key...

Materials engineering plays vital role in Solid Oxide Fuel Cell (SOFC) technology. For example, engineered porous materials are needed to support delicate electrolyte membranes, where mechanical integrity and effective diffusivity to fuel gases is critical; and to construct fuel cell electrodes, where an optimum combination of ionic conductivity, electronic conductivity, porosity and catalyst d...

■ Abstract The structural and chemical parameters determining the formation and mobility of protonic defects in oxides are discussed, and the paramount role of high-molar volume, coordination numbers, and symmetry are emphasized. Symmetry also relates to the structural and chemical matching of the acceptor dopant. Y-doped BaZrO 3-based oxides are demonstrated to combine high stability with high...

Proton-exchange membrane (PEM) fuel cells are being developed for both automotive (motive and/or auxiliary) and stationary (residential) power applications. Solid oxide fuel cells (SOFCs) also are being pursued for a number of power generation applications, including stationary (residential and utility), and automotive (auxiliary) power sources. For both of these types of fuel cells, the use of...

in this study the characteristics of two different kinds of la0.6sr0.4co0.2fe0.8o3 (lscf) powders, one in-house synthesized powder by a co-precipitation method and another one purchased from fuel cell materials co. (fcm co., usa), were compared. the co-precipitated powder was prepared by using ammonium carbonate as precipitant with a nh4+/no3- molar ratio of 2 and calcination at 1000c for 1 h....

Title of Document: ELECTROCHEMICAL OXIDATION KINETICS OF HYDROGEN AND HIGHER HYDROCARBON FUELS ON SOLID OXIDE FUEL CELLS. Oktay Demircan, Ph.D., 2007 Dissertation Directed By: Professor Bryan W. Eichhorn, Department of Chemistry and Biochemistry Solid oxide fuel cells (SOFCs) are promising electrochemical energy converting devices due to their ability to use not only hydrogen but also hydrocarb...

Direct utilization and internal reforming of gaseous fuels is investigated on symmetric-architecture metal supported solid oxide fuel cells (MS-SOFCs) with thin ceramic electrolyte scaffold backbone layers, low cost ferritic stainless steel supports both sides. Infiltrated Pr-oxide Ni/samarium-doped ceria catalysts are added to the cathode anode electrodes, respectively. Initial performance dur...

Micro-tubular solid oxide fuel cells (µT-SOFCs) are suited to a broad range of applications with power demands ranging from few watts several hundred watts. µT-SOFCs possess inherently favourable characteristics over alternate configurations such as high thermo-mechanical stability, volumetric density and rapid start-up times, lending them particular value for use in portable applications. Effi...

Hydrogen, presently, finds application as a chemical rather than a fuel in commercial operations. However, being a non-polluting source of energy, hydrogen is predicted to be the ‘‘fuel of the future’’. One of the most potential applications for hydrogen is to power fuel cells. Major automobile manufacturers are currently working towards developing fuel cell vehicles; such vehicles are expected...

Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO2/YSZ anode is active for the ...