a novel, magnetic silica sorbent with polyelectrolyte multilayers (pems) on its surface was prepared, and was used for magnetic solid phase extraction (mspe) of trace a+ via flame atomic absorption spectrometry (faas). the experimental parameters for the mspe procedure, such as the ph, type, and concentration of eluent, ultrasonic time and effects of co-existing ions were investigated. the dete...

a simple, rapid and sensitive solvent assisted-dispersive solid phase extraction method was developed for the extraction of iron(ii) prior to its spectrophotometric determination. the fe(ii) reacted with 2,4,6-tris(2-pyridyl)-1,3,5-triazine, neutralized with sodium dodecyl sulfate and extracted onto the fine particles of benzophenone which were formed upon rapid injection of a mixture of benzop...

Natural formation of the bcc modification for Co was demonstrated to occur upon precipitation of Co in supersaturated Au90Co10 alloy. The microstructural evolution was investigated by high resolution transmission electron microscopy. Co precipitation starts with the formation of very thin coherent plates along {100}Au. This initially precipitated Co was shown to be a hitherto unknown metastable...

Objective(s):The present study reports the development and validation of a sensitive and rapid extraction method beside high performance liquid chromatographic method for the determination of crocetin in human serum. Materials and Methods:The HPLC method was carried out by using a C18 reversed-phase column and a mobile phase composed of methanol/water/acetic acid (85:14.5:0.5 v/v/v) at the flow...

abstractthe oldest method for the managing of the illness is the use of medicinal plants. the use of herbal products as the first choice in self-treatment of minor conditions continues to expand rapidly across iran. this makes the safety of herbal products an important public health issue.pesticides are used widely in agriculture to increase the production by controlling the harmful insects and...

dracocephalum kotschyi (lamiaceae), as one of the remarkable aromatic plants, widely grows and also is cultivated in various temperate regions of iran. there are diverse reports about the composition of the oil of this plant representing limonene derivatives as its major compounds. there is no report on cloning of mono- or sesquiterpene synthases from this plant. in the present study, the aroma...

computational fluid dynamics (cfd) simulations of gas-solid flow through a positive low-pressure pneumatic conveyor were performed using eulerian-eulerian framework. pressure drop in pneumatic conveying pipelines, creation and destruction of plugs along the horizontal and vertical pipes, effect of 90° elbows and u-bends on cross-section concentrations, and rope formation and dispersion were num...

the occurrence and fate of trace-level contamination of pharmaceuticals in the aquatic environment has been recognized as one of the emerging issues in environmental chemistry. the effluents of wastewater treatment plants, usually directly emitted to the environment, often contain the anti-inflammatory drug diclofenac. diclofenac was chosen because it is of high consumption; by background liter...