The ability to strongly absorb light is central to solar energy conversion. We demonstrate here that the hybrid of monolayer ZrS2 and double-ring tubular B20 cluster exhibits dramatically enhanced light absorption in the entire visible spectrum. The unique near-gap electronic structure and large built-in potential at the interface will lead to the robust separation of photoexcited charge carrie...

The synthesis of 1,4,7-trimethyloxatriquinane (1), a 3-fold tertiary alkyl oxonium salt, is described. Compound 1 is inert to solvolysis with alcohols, even at elevated temperatures, but undergoes facile substitution with the strongly nucleophilic azide anion. Since an S(N)1 pathway is excluded, the only reasonable mechanistic interpretation for the reaction between 1 and N(3)(-) is S(N)2, desp...

The commonly used partial differential equations for point defect diffusion are reviewed. Special attention is given to the initial conditions of the point defect concentrations. Our numerical simulations clearly show that the assumption of initially equidistributed point defect concentrations at process temperature is justified only for a very special choice of parameters. A more general treat...

The morphology of doped polypyrrole.Cl powder changes dramatically from granular to nanofibrillar when a very small amount (1-4 mg) of V2O5 nanofibers are added to a chemical oxidative polymerization of pyrrole in aq 1.0 M HCl using (NH4)2S2O8 as the oxidant. Unlike the polyaniline system, a key synthetic requirement in the polypyrrole system is for the seed template to be "active", i.e., to be...

(Received) Scattering by a single impurity introduced in a strongly correlated electronic system is studied by exact diagonalization of small clusters. It is shown that an inert site which is spinless and unable to accomodate holes can give rise to strong resonant scattering. A calculation of the local density of state reveals that, for increasing antiferromagnetic exchange coupling, d, s and p...

In this paper we elaborate on the idea @Lohse et al., Phys. Rev. Lett. 78, 1359–1362 ~1997!# that ~single! sonoluminescing air bubbles rectify argon. The reason for the rectification is that nitrogen and oxygen dissociate and their reaction products dissolve in water. We give further experimental and theoretical evidence and extend the theory to other gas mixtures. We show that in the absence o...

The direct electrochemistry of cytochrome c at a gold electrode was investigated by cyclic voltammetry using, as promoters, microperoxidase (the haem-undecapeptide obtained by hydrolysis of cytochrome c), Fe(III)-protoporphyrin IX or protoporphyrin-IX, all entrapped in a cellulose triacetate membrane. The results indicate that these immobilized systems strongly enhance the rate of electron tran...

The dynamics of resistive switchings in nanometer-scale metallic junctions formed between an inert metallic tip and an Ag film covered by a thin Ag2S layer are investigated. Our thorough experimental analysis and numerical simulations revealed that the resistance change upon a switching bias voltage pulse exhibits a strongly non-exponential behaviour yielding markedly different response times a...

an r-module m is called strongly noncosingular if it has no nonzero rad-small (cosingular) homomorphic image in the sense of harada. it is proven that (1) an r-module m is strongly noncosingular if and only if m is coatomic and noncosingular; (2) a right perfect ring r is artinian hereditary serial if and only if the class of injective modules coincides with the class of (strongly) noncosingula...

drying of green peas in a fluidized bed dryer (fbd) with inert particle, heated by combined sources of hot air and infrared (ir) radiation, has been experimentally and theoretically studied. for this purpose, an experimental set up was constructed. this setup was composed of a cylindrical bed dryer containing some inert particles which are fluidized by hot air. some infrared lamps were also pla...