Density-functional tight-binding molecular dynamics (DFTB/MD) methods were employed to demonstrate single-walled carbon nanotube (SWNT) nucleation resulting from thermal annealing of SiC nanoparticles. SWNT nucleation in this case is preceded by a change of the SiC structure from a crystalline one, to one in which silicon and carbon are segregated. This structural transformation ultimately resu...

Crystallization behavior of melt-blended polypropylene (PP)/single wall carbon nanotube (SWNT) composites has been studied using optical microscopy and differential scanning calorimetry. Polypropylene containing 0.8 wt% SWNT exhibits faster crystallization rate as compared to pure polypropylene. PP/SWNT fibers have been spun using typical polypropylene melt spinning conditions. The PP crystalli...

Poly(aminobenzene sulfonic acid) (PABS) and polyethylene glycol (PEG) were covalently attached to single-walled carbon nanotubes (SWNTs) to form water-soluble graft copolymers. Quantitative near-IR (NIR) spectroscopic studies of these SWNT graft copolymers indicate a water solubility of about 5 mg/mL, and atomic force microscopy studies show a fairly uniform length and diameter. On the basis of...

We report a numerical investigation on the catalytic growth mechanism of a single-walled carbon nanotube (SWNT) inside a template SWNT, that is, formation of a double-walled carbon nanotube (DWNT). The molecular dynamics simulations together with complementary ab inito calculations suggest that the DWNT formation from thermally annealed metallocene-encapsulating SWNT goes through formation of m...

We report a rapid and efficient procedure to functionalize SWNT where free radicals generated at room temperature by a redox reaction between reduced SWNT and diacyl peroxide derivatives were covalently attached to the SWNT wall.

Table S1. Host materials and references for Figure 5 in the main text. Reference numbers are those used in the main text. Filler material Host material Reference SWNT PDMS [15] SWNT epoxy [18] SWNT polystyrene [14] SWNT PEDOT-PSS [21] MWNT PDMS [3] MWNT epoxy [17] MWNT polystyrene [11] MWNT polyurethane-urea [10] EG polystyrene [12] EG NBR [5] silver particles PDMS [1] CB polystyrene [16] CB po...

This Article contains typographical errors. In the Results section under subheading 'Nanotube-based compact all-fiber triple-wavelength laser sys-tem' , " The dispersion parameter of these three CFBGs is ~2.2 ps 2 /cm with the length of ~10 mm " should read: " The dispersion parameter of these three CFBGs is − 2.2 ps 2 /cm with the length of ~10 mm ". In addition, " Fig. 1(d) shows the absorpti...

The growth process of vertically aligned single-walled carbon nanotube (SWNT) films was investigated by means of in situ optical analysis and scanning electron microscopy. The measurements reveal that the growth of the SWNT film decreases after longer reaction times. This decrease is attributed to a combination of a diminishing growth rate and burning of the SWNTs due to oxygen in the growth ch...

We report surprisingly efficient photocurrent generation at individual single-walled carbon nanotube (SWNT) /poly(3-hexylthiophene-2,5-diyl) (P3HT) junctions. Contrary to previous prediction, both semiconducting SWNTs (s-SWNTs) and metallic SWNTs (m-SWNTs) function as efficient hole acceptors. By active tuning of SWNTs' Fermi level, we confirm that P3HT p-dopes both s-SWNT and m-SWNT, and the w...

Asymmetrically functionalized single-wall carbon nanotubes (SWNTs) have been prepared by a covalent reaction of an 11-mercaptoundecanol-modified Au surface with oxidized SWNT cylinders. While one end of the tubes is attached to gold substrate via ester groups, the free carboxylic substituents on the other end can be either ionized (CO2-) or esterified (CO2Et), creating a donor-acceptor asymmetr...