نتایج جستجو برای: tautomerization
تعداد نتایج: 374 فیلتر نتایج به سال:
The mechanism of the title reaction is found to consist of three steps by DFT calculations: (1) N(2) dissociation, (2) intramolecular Ag-carbene addition, and (3) proton transfer. The N(2) dissociation is turnover determining. The product 3-alkylideneoxindole is favored in tautomerization with 3-acetyl-2-hydroxyindole.
An efficient sensor for Zn(2+) and Cu(2+) was designed based on different binding modes. The sensor displays ratiometric signals for Zn(2+), due to the Zn(2+)-triggered amide tautomerization; while dual-mode selective behaviors for Cu(2+) result from the deprotonation of the amide tautomer.
We have investigated deuterium-substitution and solvent effects for the keto-enol tautomerization of acetylacetone (Hacac) confined in 10 – 100 nm scale spaces (called extended-nano spaces) based on NMR spectroscopic results, and elucidated the tautomeric reaction mechanisms in the extended-nano spaces.
An efficient palladium-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols has been developed via capture of the active tautomers. A wide variety of 2,5-disubstituted and 2,4,5-trisubstituted pyrazolidinones have been synthesized with up to 96% and 95% ee, respectively. The hydrogenation pathway includes Brønsted acid promoted tautomerization of pyrazol-5-ols and Pd-catalyz...
A detailed procedure for the quantitative determination of metanephrine and normetanephrine is given. Epinephrine and norepinephrine are eliminated by selective adsorption on an alumina column. Metanephrine and normetanephrine are isolated with a cation-exchange resin. Fluorescence is developed by a two-step ferricyanide oxidation at two different pH values followed by tautomerization. The conc...
A novel luminescent Zn(2+) ions chemosensor, a cyclometalated platinum(II) bipyridyl acetylide complex, was designed. Of particular significance is that it shows a high sensitivity towards Zn(2+) ions without interference from other biologically important cations in acetonitrile. The tautomerization of amide favors detecting Zn(2+) ions among other HTM (heavy and transition metal) ions in aqueo...
The copper-catalyzed ketenimine formation reaction of 1-(o-acetamidophenyl)propargyl alcohols with various sulfonyl azides is found to undergo a concomitant intramolecular nucleophile attack to generate 1,2-dihydro-2-iminoquinolines after aromatization (via elimination of acetyl and hydroxy groups) and tautomerization. The reaction produces 4-substituted and 3,4-unsubstituted title compounds in...
Ir(I)-induced tautomerization of a pyridine moiety to a carbene in 2,3-bipyridyls has been successfully achieved where an amide group plays a key role as a hydrogen-bonding acceptor and the carbene tautomer is stabilized by both chelation effect and by hydrogen-bonding.
A novel one-pot strategy for the synthesis of 3-trifluoromethylquinoxalines from N-aryl enamines and nitromethane was developed. The tandem reaction is achieved through nitrosation of alkenes, tautomerization and cyclization, which can be applicable to a wide range of enamines with excellent functional group tolerance and afford quinoxalines in moderate to good yields.
Surface-enhanced Raman scattering (SERS) spectra of a metal-complexing ligand, immobilized to a silver electrode surface, exhibits significant structural changes upon application of modest potentials. A detailed spectroscopic investigation shows that the potential applied to the electrode surface governs the tautomerization equilibrium of the immobilized ligand, p-((8-hydroxyquinoline)azo)benze...
نمودار تعداد نتایج جستجو در هر سال
با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید