The octa-hedral cluster core of the anion in the structure of the title compound, (C(16)H(36)N)(3)[Mo(6)(C(4)H(9)S)(6)(μ(3)-Cl)(7)(μ(3)-S)]·2H(2)O, has -3 site symmetry. Two μ(3)-Cl atoms fully occupy positions in the cluster core, while the remaining six positions are statistically occupied by Cl and S atoms in a 1:5 ratio. The fully occupied Cl-atom positions are located on sites with 3 symme...

In the title compound, (n-C(4)H(9))(4)N(+)·C(7)H(5)O(3) (-)·2H(2)O, the carboxyl-ate group is twisted slightly out of the plane of the attached benzene ring, the two C-C-C-O torsion angles being -8.9 (2) and -10.7 (2)°. The anion inter-acts with two water mol-ecules through several O-H⋯O hydrogen bonds, forming wide ribbons along the a axis constructed from two anion-water chains. These ribbons...

liquid membrane processes have attracted many interests in recent years for removal of heavy metals such as cadmium from industrial wastewaters. in this study, a modified hybrid liquid membrane system is introduced. the setup is worked by applying the water-insoluble dioctyl phthalate as the organic solvent. n-octanol and tetra butyl ammonium bromide are added to the organic phase to increase t...

We have introduced a selective synthesis of tertiary amines using alkyl halide and ammonium salts as the amine sources in water. This green process has outstanding superiorities, such as being eco-friendly, possessing ammonium salts, and using water as a green solvent in the absence of organic ligands or catalysts. It is worth mentioning that the presence of t-Butyl alcohol and potassi...

The asymmetric unit of the title compound, C48H54O5S4·N(C2H5)4 (+)·Cl(-), contains two tetra-tert-butyl-[(benzo-yl)meth-oxy]-trihy-droxy-tetra-thia-calix[4]arene mol-ecules, two tetra-ethyl-ammonium cations and two chloride anions. The two calixarene molecules in the asymmetric unit each display a cone conformation. There are no significant differences between the two independent molecules. The...

Trihexyltetradecylphosphonium (P6,6,6,14) salts of luminescent anionic Pt(II) complexes, (P6,6,6,14)[PtX2(ppy)] (X = Cl-, Br-; ppy 2-phenylpyridinate), are synthesized and photofunctional thin films with crystal/liquid bi-stability fabricated. In particular, the chloride complex provides a film exhibiting thermo- mechano-triggered luminescence ON/OFF switching at ambient temperature, which is b...

The nature of solvent-biomolecule interactions is generally weak and non-specific. The addition of ionic liquids (ILs), which have emerged as a new class of solvents, strengthen the stability of some proteins whereas the same ILs weaken the stability of some other proteins. Although ILs are commonly used for the stabilization of biomolecules, the bimolecular interactions of their stabilization-...

Liquid membrane processes have attracted many interests in recent years for removal of heavy metals such as cadmium from industrial wastewaters. In this study, a modified hybrid liquid membrane system is introduced. The setup is worked by applying the water-insoluble dioctyl phthalate as the organic solvent. N-octanol and tetra butyl ammonium bromide are added to the organic phase to increase t...