Silver nanoparticle-containing silica sol–gel coatings were synthesised using tetraethylorthosilicate (TEOS), HNO3 and AgNO3 as the main precursors and 3-(2-aminoethylamino)propyl trimethoxysilane (DIAMO) as a stabiliser. The stability and the barrier properties of the coatings were studied by means of UV/Vis spectroscopy, FTIR reflection absorption spectroscopy (IRRAS), spectroscopic Ellipsome...

Bioencapsulation of microbial cells in silica-based matrices has proved to be a good strategy to enhance the biosynthetic capabilities and viability of bioproducers. In the present study, mycelium and pellet cultures of strain Aspergillus oryzae PP were successfully immobilized in sol-gel hybrid matrices composed of tetraethylorthosilicate as an inorganic precursor, 5% (w/v) starch and 10 or 15...

Silicon dioxide films were prepared on p-type Si (100) substrates by sol electrophoretic deposition (EPD) using tetraethylorthosilicate (TEOS) at low temperature. According to the variation of sol dipping conditions, we estimated the characteristics of SiO2 films, such as composition, surface morphology, wet etch rate, breakdown voltage, etc. The growth rate of the film increased linearly with ...

An aqueous hybrid inorganic/organic sol-gel solution composed of tetraethylorthosilicate (TEOS), methyltriethoxysilane (MTES) and (3-glycidyloxypropyl)trimethoxysilane (GPTMS) was applied on ZnFe (14 wt.% Fe) electrodeposited steel as a sacrificial layer. Two precursor contents were studied: 10 (SG10) 30 % (SG30). First, the morphology thickness films assessed by Scanning Electron Microscopy (S...

Poly(methyl acrylate) (PMA) + SiO2 composites were synthesized via a sol-gel reaction. The base acrylic copolymers with a content of alkoxysilane groups were prepared by co-polymerization of methylacrylate (MA) with 3-(trimethoxysilyl) propylmethacrylate (3MPS) or vinyltrimethoxysilane (VTMS); the products were cocondensed with tetraethylorthosilicate (TEOS). The PMA + SiO2 hybrids were charact...

Silica nanoparticles with a narrow particle size distribution and controlled diameters of 10-20 nm are synthesized via hydrolysis and hydrothermal aging of tetraethylorthosilicate in an aqueous L-lysine solution. Cryo-transmission electron microscopy (cryo-TEM) reveals that the silica nanoparticles assemble to form close-packed nanoparticle crystals over short length scales on carbon-coated gri...

A new method for preparing magnetic iron oxide nanoparticles coated by organic dye-doped silica shell was developed in this article. Iron oxide nanoparticles were first coated with dye-impregnated silica shell by the hydrolysis of hexadecyltrimethoxysilane (HTMOS) which produced a hydrophobic core for the entrapment of organic dye molecules. Then, the particles were coated with a hydrophilic sh...

It has been reported in the literature that the composition Unsupported silica membranes were prepared by acid-catalyzed of the synthesis solution influences the structure of the spehydrolysis and condensation of tetraethylorthosilicate. The possicies in the sol (3) and, hence, the final structure of the bility of tailoring the pore size and porosity of microporous silica membrane. This possibi...

In silicon surface micromachining, anhydrous HF GPE process was verified as a very effective method for the dry release of microstructures. The developed gas-phase etching (GPE) process with anhydrous hydrogen fluoride (HF) gas and alcoholic vapor such as methanol, isopropyl alcohol (IPA) was characterized and its selective etching properties were discussed. The structural layers are P-doped mu...

This paper presents for the first time the preparation of glass layers, suitable for the anodic bonding of two silicon substrates using a spin-on glass. In this process a liquid sol solution is used within a spin coating process. The solution is a mixture based on silica sol, organic silicon containing compounds, like TEOS (Tetraethylorthosilicate), and a sodium salt all dissolved in ethanol. A...