The thermal cis-to-trans isomerisation process has been studied for a series of para-, ortho- and polyhydroxy-substituted azobenzenes in different solvents. The kinetics of the thermal back reaction for the p-hydroxy-substituted azobenzenes depend strongly on the nature of the solvent used, with relaxation times ranging from 200-300 milliseconds in ethanol to half an hour in toluene. Otherwise,...

Measurements of the thermal properties of nanoscale electron systems have ignored the effect of electrical noise radiated between the electron gas and the environment, through the electrical leads. Here we calculate the effect of this photon-mediated process, and show that the low-temperature thermal conductance is equal to the quantum of thermal conductance, GQ = pi2kB2T/3h, times a coupling c...

Thermal shape fluctuations of grafted microtubules were studied using high resolution particle tracking of attached fluorescent beads. First mode relaxation times were extracted from the mean square displacement in the transverse coordinate. For microtubules shorter than approximately 10 microm, the relaxation times were found to follow an L2 dependence instead of L4 as expected from the standa...

Using an isospin-dependent transport model, we have studied the isospin and momentum relaxation times in the heavy residues formed in heavy-ion collisions at intermediate energies. It is found that only at incident energies below the Fermi energy, chemical or thermal equilibrium can be reached before dynamical instability is developed in the heavy residues. Also, the isospin relaxation time is ...

Proton nuclear magnetic resonance (1H NMR) experiments have been performed to measure the spin-lattice, T1, and spin-spin, T2, relaxation times of the three functional groups in water/methanol mixtures at different methanol molar fractions (XMeOH=0, 0.04, 0.1, 0.24, 0.5, 1) as a function of temperature in the range 205 K<T<295 K. The measured relaxation times in the mixtures, at all the methano...

The relaxation of long-lived states (LLS) corresponds to the slow return to statistical thermal equilibrium between symmetric and antisymmetric proton spin states. This process is remarkably sensitive to the presence of external spins and can be used to obtain information about partial unfolding of proteins. We detected the appearance of a destabilized conformer of ubiquitin when urea is added ...

We investigate the magnetization relaxation of a one-dimensional helimagnetic system coupled to interacting itinerant electrons. The relaxation is assumed to result from the emission of plasmons, the elementary excitations of the one-dimensional interacting electron system, caused by slow changes of the magnetization profile. This dissipation mechanism leads to a highly nonlocal form of magneti...