High-flux optical systems (HFOSs) are optical concentrators used to increase the radiative flux of the natural terrestrial solar irradiation. High radiative flux concentration leads to high energy density in solar receivers which allows to obtain high temperatures. In solar thermochemical applications, the hightemperature heat drives endothermic thermochemical reactions. HFOSs have been deploye...

Jarosite, a potassium (sodium) iron sulphate hydrated mineral, has recently been identified on the martian surface by the Opportunity rover. Using recent thermochemical data [Drouet and Navrotsky, 2003, Geochim. Cosmochim. Acta 67, 2063–2076; Forray et al., 2005, Geochim. Cosmochim. Acta, in press], we calculate the equilibrium decomposition curve of jarosite and show that it is thermodynamical...

Approach • Review all published papers, reports, patents, etc. in the past 25+ years that relate to thermochemical water-splitting cycles, in general, and solar driven cycles, in particular. • Use FactSageTM program to perform chemical equilibrium calculations. • Employ HYSYS/ASPEN Plus chemical process simulation (CPS) program for developing process flowsheet, process analyses and optimization...

The purpose of this article is to present, for the chemical vapour deposition process, mass transport models with near local thermochemical equilibrium imposed in the gas-phase and at the deposition surface. The theoretical problems arising from the linking of the two approaches, thermodynamics and mass transport, are shown and a solution procedure is proposed. As an illustration, selected resu...

Stratospheric heating, condensation, convective transport of non-equilibrium species, and deep radiative energy transport are important processes in the atmospheres of the solar jovian planets. They likely affect the atmospheres of extrasolar giant planets and brown dwarfs as well. Stratospheric temperatures control thermal fluxes in strong molecular bands, and may dramatically affect observed ...

The heat of the reaction NAD(+)+propan-2-ol=NADH+acetone+H(+) was determined to be 42.5+/-0.6kJ/mol (10.17+/-0.15kcal/mol) from equilibrium measurements at 9-42 degrees C catalysed by yeast alcohol dehydrogenase. With the aid of thermochemical data for acetone and propan-2-ol the values of DeltaH=-29.2kJ/mol (-6.99kcal/mol) and DeltaG(0)=22.1kJ/mol (5.28kcal/mol) are derived for the reduction o...

Thermochemical conversion of biomass offers an efficient and economically process to provide gaseous, liquid and solid fuels and prepare chemicals derived from biomass. Computational fluid dynamic (CFD) modeling applications on biomass thermochemical processes help to optimize the design and operation of thermochemical reactors. Recent progression in numerical techniques and computing efficacy ...

Thermochemical equilibrium and kinetic calculations are used to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs). The chemical behavior of individual Sand P-bearing gases and condensates is determined as a function of pressure, temperature, and metallicity. The results are independent of particular model atmospheres and, in principle, the...

Thermochemical relaxation behind a normal shock in Mars and Titan gas mixtures is simulated using a CFD solver, DPLR, for a hemisphere of 1 m radius; the thermochemical relaxation along the stagnation streamline is considered equivalent to the flow behind a normal shock. Flow simulations are performed for a Titan gas mixture (98% N2, 2% CH4 by volume) for shock speeds of 5.7 and 7.6 km/s and pr...

(22 articles) energy (149 articles) materials science collections Articles on similar topics can be found in the following Email alerting service here in the box at the top right-hand corner of the article or click Receive free email alerts when new articles cite this article-sign up We present a comprehensive thermodynamic and kinetic analysis of the suitability of cerium oxide (ceria) for the...