let h be a finite dimensional complex hilbert space, b(h)+ be the set of all positive semi-definite operators on h and phi is a (not necessarily linear) unital map of b(h) + preserving the entropy-gibbs transformation. then there exists either a unitary or an anti-unitary operator u on h such that phi(a) = uau* for any b(h) +. thermodynamics, a branch of physics that is concerned with the study...

Finite-time thermodynamics is the extension of traditional reversible thermodynamics to include the extra requirement that the process in question goes to completion in a specified finite length of time. As such it is by definition a branch of irreversible thermodynamics, but unlike most other versions of irreversible thermodynamics, finite-time thermodynamics does not require or assume any kno...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

The socio-thermodynamics of a population of two competing species exhibits strong analogies with the thermodynamics of solutions and alloys of two constituents. In particular we may construct strategy diagrams akin to the phase diagrams of chemical thermodynamics, complete with regions of homogeneous mixing and miscibility gaps.

this paper aims at studying a trigeneration system, based on an internal combustion engine and a steam ejector refrigeration system. the designed cycle is to generate cooling and heating energies, and supply power simultaneously. the cycle is studied from thermodynamics point of view and for this purpose, the first law of thermodynamics is applied to all components of the cycle. the efficiency ...

Black holes have their own thermodynamics including notions of entropy and temperature and versions of the three laws. After a light introduction to black hole physics, I recollect how black hole thermodynamics evolved in the 1970’s, while at the same time stressing conceptual points which were given little thought at that time, such as why the entropy should be linear in the black hole’s surfa...

It is probably not a coincidence that two of the pioneers of thermodynamics, Helmholtz and Mayer, were physicians. Thermodynamics studies the transformations of energy, and such transformations ceaselessly take place in all living systems (probably with important differences between the states of health and disease). Moreover, thermodynamics studies the elusive notions of order and disorder, wh...

This paper presents the Web-based Thermodynamics Tables Wizard and how it can be used for online courses or web-teaching to accommodate the need of students at different levels in looking up thermodynamics properties. It can be used as a stand-alone study aid or an add-on component for any online Thermodynamics course. The implementation of this Web-based module has greatly enhanced the learnin...