The current approach involves the kinetic investigation of Thiobenzamide (TB) and cyclohexanone thiosemicarbazone (CTSC) in solution with 3-chloroacetylacetone(3-CAA). study revealed a second-order rate constant respect to both reactants, thioamide an α-halo carbonyl compound. energy activation (Ea) was found be Ea 48.8176 kJ/mol/K for thiobenzamide 33.08692157 Cyclohexanone thiosemicarbazone. ...

The reaction of three [FeII(TSC)2] complexes, where TSC is a pyridine-substituted thiosemicarbazone the DpT or BpT families, with H2O2 in acetonitrile solution does not result accumulation of...

Three copper(II) complexes of salicylaldehyde N(4)-phenyl thiosemicarbazone (H2L ) and two copper(II) complexes of N(4)-cyclohexyl thiosemicarbazone (H2L ) have been synthesized and characterized by different physicochemical techniques like magnetic studies and electronic, infrared and EPR spectral studies. The complexes 1⁄2ðCuL1Þ2 12H2O ð1Þ and [(CuL )2] (4) having dimeric structure. The thios...

Evaluation the Effect of Chemotherapy Drugs and Thiosemicarbazone Complexes on Expression URHC CASC15 LncRNAs in Acute Lymphoblastic Leukemia Cell Line

Anticancer drugs A series of monoand dinuclear (η-arene) ruthenium(II) complexes were prepared by reaction of thiosemicarbazone ligands derived from benzaldehyde and ruthenium(II) precursors of the general formula [Ru(η-arene)(μ-Cl)Cl]2, where arene=p-PrC6H4Me or C6H5C3H6COOH. These complexes were characterized by NMR and IR spectroscopy, ESI-mass spectrometry and elemental analysis. The molecu...