نتایج جستجو برای: transition metal ions
تعداد نتایج: 546120 فیلتر نتایج به سال:
The tetra azophenylcalix[4]arene with ortho-ester group was applied for determination of transition metal ions using spectrophotometer. In this case, the derivatives with ortho-ester group turned out the complexing formation selectively with transition metal ions over alkali, alkaline earth metal ions. From those, this study used the molecular mechanic method MM+ and molecular dynamic simulatio...
Previous studies (KALB, A. J., AND LEVITZKI, A. (1968) Biochem. J. 109, 669; SHOHAM, M., KALB, A. J., AND PECHT. I. (1973) Biochemistry 12, 1914) were interpreted as showing that transition metal and calcium ions must be bound to concanavalin A before this lectin can bind sugars. In contrast, we find that the addition of calcium ions fails to affect the following properties of manganese concana...
Electronic effects and the bond network are the two factors that cause out-of-center distortions in octahedral d(0) transition metal oxide fluoride anions. Overlap between filled oxide p orbitals and vacant cation d orbitals results in strong, short metal-oxide bonds causing the metal ion to distort toward the oxide ligand. This primary, electronic distortion is not dependent on the extended st...
Abstract This chapter introduces a general protocol to transfer metal ions from aqueous solution to an organic medium, which involves mixing the aqueous solution of metal ions with an ethanolic solution of dodecylamine (DDA), and extracting the coordinating compounds formed between metal ions and DDA into toluene. This protocol could be applied toward transferring a wide variety of transition m...
In transition metal oxides, preferential occupation of specific d orbitals on the transition metal ion can lead to the development of a long-range ordered pattern of occupied orbitals. This phenomenon, referred to as orbital ordering, is usually observed indirectly from the cooperative Jahn-Teller distortions (CJTDs) that result as a consequence of the orbital ordering. This paper examines the ...
Capacity and voltage fading of layered structured cathode based on lithium transition-metal oxide is closely related to the lattice position and migration behavior of the transition-metal ions. However, it is scarcely clear about the behavior of each of these transition-metal ions in this category of cathode material. We report direct atomic resolution visualization of interatomic layer mixing ...
A new modelling study of the role of transition metal ions on cloud chemistry has been performed. Developments of the Model of Multiphase Cloud Chemistry (M2C2; Leriche et al., 2001) are described, including the transition metal ions reactivity emission/deposition processes and variable photolysis in the aqueous phase. The model is then applied to three summertime scenarios under urban, remote ...
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