Loss of lithium in the initial cycles appreciably reduces the energy density of lithium-ion batteries. Anode prelithiation is a common approach to address the problem, although it faces the issues of high chemical reactivity and instability in ambient and battery processing conditions. Here we report a facile cathode prelithiation method that o ers high prelithiation e cacy and good compatibili...

Beyond the state of the art, EVOLVE aims at the development of a new cell architecture for SOFC, combining benefits of existing Anode Supported (high power density, lifetime) and Metal Supported cell (redox stability) architectures, while limiting the issue of sulphur poisoning by using enhanced perovskite anode materials. The core component is based on a composite anode substrate made of porou...

MnO2@PPy core-shell micromaterials are prepared by chemical polymerization of pyrrole on the MnO2 surface. The polypyrrole (PPy) is formed as a homogeneous organic shell on the MnO2 surface. The thickness of PPy shell can be adjusted by the usage of pyrrole. The analysis of SEM, FT-IR, X-ray photoelectron spectroscopy (XPS), thermo-gravimetric analysis (TGA), and XRD are used to confirm the for...

We report a derivative spectroscopic method for determining insulator-to-semiconductor transition during sol-gel metal-oxide semiconductor formation. When an as-spun sol-gel precursor film is photochemically activated and changes to semiconducting state, the light absorption characteristics of the metal-oxide film is considerable changed particularly in the ultraviolet region. As a result, a pe...

Metal oxide anode materials are affected by severe volume expansion and cracking in the charging/discharging process, resulting low capacity poor cycle stability, which limits their application lithium-ion batteries (LIBs). Herein, a new strategy is uncovered for preparing spinel-structured, multi-component transition metal oxide, (Ni,Co,Mn)Fe2O4−x, with oxygen vacancies as an LIB material. The...

lithium-ion batteries due to their higher energy density and lower associated environmental impacts comparing to the other batteries, recently have been highly considered. the materials used in anode, are one of the most important parts affecting batteries’ energy density and environmental impacts. the aim of this study is to investigate how environmental emissions of different materials as ano...

Silicon and graphene are promising anode materials for lithium-ion batteries because of their high theoretical capacity; however, low volumetric energy density, poor efficiency and instability in high loading electrodes limit their practical application. Here we report a large area (approximately 15 cm × 2.5 cm) self-standing anode material consisting of molecular precursor-derived silicon oxyc...

In this paper, we have focused on the preparation and characterization of copper oxide nanoparticles by solid state thermal decomposition of copper(I) iodide in the presence of thiosemicarbazone ligands without the need for a catalyst, employing toxic solvent, template or surfactant and complicated equipment, which makes it efficient, one-step, simple and environment-friendly. CuO nanoparticles...

Doped Bi-based oxides were investigated as potential anode materials for direct hydrocarbon solid oxide fuel cells ~SOFCs! at intermediate temperatures. (Bi2O3)0.85(Ta2O5)0.15 met this criterion most successfully. A fraction of Bi2O3 in this material was reduced to BiO and Bi metal under fuel conditions, which yielded high conductivities ~,1 S cm! based on oxide ions and electrons above 500°C. ...