A process for the gram scale synthesis of the oxygen bridged dimer of boron subphthalocyanine, μ-oxo-(BsubPc)2, has been developed. During the development it was found that a wide range of reaction pathways under diverse conditions lead to μ-oxo-(BsubPc)2 formation. However, obtaining μ-oxo-(BsubPc)2 as the main reaction product in appreciable yields and its subsequent isolation were extremely ...

A rhodium-catalysed stitching reaction between 2-(silylethynyl)arylboronates and 2-(silylethynyl)aryl bromides has been developed for the synthesis of unsymmetric dibenzo[a,e]pentalenes. The introduction of appropriately sized silyl groups on the starting substrates led to a high crossover selectivity without using an excess amount of either substrate. The present stitching reaction could produ...

We present greedy unsymmetric collocation schemes for solving linear elliptic partial differential equations using radial basis functions. The proposed approach circumvents the ill-conditioning problem associated with the standard collocation technique and enables the efficient solution of problems requiring a large set of collocation points. Numerical studies indicate that the accuracy of gree...

Recent engineering applications successfully introduced unsymmetric meshless local Petrov-Galerkin (MLPG) schemes. As a step towards their mathematical analysis, this paper investigates nonstationary unsymmetric Petrov-Galerkin-type meshless kernel-based methods for the recovery of L2 functions from finitely many weak data. The results cover solvability conditions and error bounds in negative S...

Fast algorithms, based on the unsymmetric look-ahead Lanczos and the Arnoldi process, are developed for the estimation of the functional (f)= uf(A)v for xed u; v and A, where A∈Rn×n is a large7 scale unsymmetric matrix. Numerical results are presented which validate the comparable accuracy of both approaches. Although the Arnoldi process reaches convergence more quickly in some cases, it 9 has ...

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An efficient method towards synthesis of 1,10-phenanthrolines is described. Through Lewis acid-catalyzed annulation reaction between 3-ethoxycyclobutanones and 8-aminoquinolines, a variety of unsymmetric and symmetric 1,10-phenanthroline derivatives were readily prepared with high regioselectivity at room temperature.

An unsymmetric tetracarboxylic ligand collaborates with 4,4'-bipyridine to induce spontaneous resolution to form homochiral 3D coordination frameworks, while the use of longer dipyridyl ligands instead of 4,4'-bipyridine leads to isoreticular but heterochiral frameworks.