Fully reversible photoswitching of the coordination mode of the ligand MeN4Py (1,1-di(pyridin-2-yl)-N,N'-bis(pyridin-2-yl-methyl)-ethan-1-amine) in its ruthenium(II) complex with visible light is reported. Irradiation with visible light results in dissociation of a pyridyl moiety, which is reversed by irradiation at 355 nm.

This paper reports that the introduction of elemental red phosphorus (RP) into TiO2 can shift the light absorption ability from the UV to the visible region, and confirmed that the optimal RP loading and milling time can effectively improve the visible light driven-photocatalytic activity of TiO2. The resulting RP-TiO2 nanohybrids were characterized systematically by a range of techniques and t...

Introduction: Rapid population growth and industrialization have increased chemical pollutants. Some studies show that employee exposure to formaldehyde in industrial places, hospitals, and laboratory settings is more than the allowed limits. Therefore, it is necessary to implement a proper control system to reduce this exposure. This study aimed to synthesize Ag3PO4/TiO2 nanocomposite, determi...

Here we present a method to produce TiO2 nanocrystals coated by thin layer of graphitic carbon. The coating process was prepared via chemical vapor deposition (CVD) with acetylene used as a carbon feedstock with TiO2 used as a substrate. Different temperatures (400°C and 500°C) and times (10, 20, and 60 s) of reaction were explored. The prepared nanocomposites were investigated by means of tran...

BACKGROUND: This work deals with the development of an active heterogeneous catalyst for selective organic synthesis under both visible light and UV irradiation to utilize efficiently solar light. Very few studies have been reported on the selective photooxidation performance of multimetal oxide materials under visible light irradiation. The photocatalytic degradation of azodyes was investigate...

Ag-Fe2O3 and Sn-doped Ag-Fe2O3 nanocomposite photocatalysts were optimized by scanning photoelectrochemical microscopy (SPECM) as a potential photoelectrochemical material for visible light irradiation (λ g 420 nm). The photocurrent vs potential response and the action spectra were investigated in a three-electrode cell. Among different mole ratios, the composition of nanocomposite with 50%Ag-5...

Visible-light-induced water splitting was achieved by increasing the visible-light sensitivity of AgTaO3, by the introduction of Nb, generating AgTa1-xNbxO3. After grafting NiO onto AgTa0.7Nb0.3O3, simultaneous, catalytic liberation of H2 and O2 at a molar ratio of ∼2 : 1 was achieved from pure water under only visible-light irradiation.

A photo excitation fast flow reactor coupled with a single-photon ionization (118 nm, 10.5 eV) time-of-flight mass spectrometry (TOFMS) instrument is used to investigate reactions of neutral MnmOn clusters with C2H4 under visible (532 nm) light irradiation. Association products Mn2O5(C2H4) and Mn3O6,7(C2H4) are observed without irradiation. Under light irradiation, the Mn2O5(C2H4) TOFMS feature...

The selective incorporation of 5-bromodeoxyuridine (BrdU) into mitochondrial DNA (mit-DNA) in the LM(TK-) ClID cell line, a thymidine kinase-deficient derivative of L fibroblasts with persistent mitochondrial enzyme activity, has been utilized to specifically damage mit-DNA by 'visible' light irradiation. ('Visible light' indicates the source of light used, although the components most active p...

The selective incorporation of 5-bromodeoxyuridine (BrdU) into mitochondrial DNA (mit-DNA) in the LM(TK") ChD cell line, a thymidine kinase-deficient derivative of L, fibrobla8ts with persistent mitochondrial enzyme activity, has been utilized to specifically damage mit-DNA by 'visible' light irradiation. ('Visible light' indicates the source of light used, although the components most active p...