The in-situ anionic polymerization of ε-caprolactam (ε-CL) to polyamide-6 enables the production large, near net shape fiber reinforced composites by thermoplastic resin transfer molding. For propagation flow front as well for progress solidification, simultaneous processes and crystallization corresponding reaction kinetics play a central role. To investigate these processes, preparation react...

N-alkylation of N,N'-(hexane-1,6-diyl)bis(4-methylbenzenesulfonamide) with allyl bromide and subsequent Prilezhaev reaction with m-chloroperbenzoic acid to give N,N'-(hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide) is described. This twofold alkylation was performed in aqueous solution, whereby α-, and randomly methylated β-cyclodextrin were used as adequate phase transfer...