Transformation of Al(NO3)3∙9H2O (upon heating in the range of 20-1200 °C) into blends of amorphous and crystalline boehmite (210-525 °C), amorphous alumina and crystalline γ-Al2O3 (850 °C), and crystalline α-Al2O3 (1100 °C) was analyzed using X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), infrared (IR) spectroscopy, thermogravimetry, and low-temperature nitro...

Objetivo: En este estudio se evaluó el efecto de la modificación con óxido zinc del soporte convencional en catalizadores hidrodesulfuración (HDS) a base polioxometalato Anderson-Evans NiMo5W. Metodología: Los fueron sintetizados por método co-precipitación NiMo5W sobre Al2O3. caracterizaron FRX, MEB/EDS, CHONS, propiedades texturales, FT-IR, Raman y titulación potenciométrica n-butilamina. Res...

Abstract: The catalytic hydrogenation of lignin-derived monophenols with high efficiency and selectivity is important for the sustainable production of chemicals and fuels. Here, Pd/γ-Al2O3 was prepared via impregnation and used as catalyst for the hydrogenation of phenols to cyclohexanols under mild conditions in aqueous solution. 3 wt. % Pd/γ-Al2O3 exhibited good catalytic activity for the se...

A series of experiments were performed for toluene decomposition from a gaseous influent at normal temperature and atmospheric pressure by nonthermal plasma coupled with a combination of catalysts technology. Nonthermal plasma was generated by dielectric barrier discharge. γ-Al2O3 was used to be a sorbent and a catalyst carrier. Nanocatalysts were MnO2/γ-Al2O3 coupled with modified ferroelectri...

Introduction Alkaline earth oxides (AEOs) such as BaO have received considerable attention for their application in the lean-burn engine NOx storage/reduction (NSR) technology [1]. Previous experimental investigations have indicated that barium nitrate is the most stable form of the stored NOx in Ba-containing NSR catalysts. Two distinctive types of barium nitrates, Ba(NO3)2, i.e. “surface” and...

Four catalysts—1%Pd-2%Mn/γ-Al2O3, 1%Pd/γ-Al2O3, 2%Mn/γ-Al2O3 and γ-Al2O3—were synthesized via a sol–gel method characterized using various techniques to evaluate their physicochemical, textural, surface acidic properties. They were used in the catalytic transformation of ozone nitrogen oxides situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) analysis. Different consecuti...

Wettability alteration is one of the most important methods for oil recovery from sandstone and carbonate reservoirs. The effects of salinity, pH, temperature, and chemicals such as surfactants and fatty acids on the alteration of the wettability were described in previous studies. In recent years, attention has been directed to nanoparticles as a wettability alteration agent. The effect of som...

A heat exchanger using nanofluid needs to operate at optimum mass concentration level to get the maximum heat transfer performance. A numerical analysis is performed on the heat transfer and pressure drop of water-based γ-Al2O3 nanofluid gasketed-plate heat exchanger to specify its optimum conditions. Cold water will be heated by γ-Al2O3/water nanofluid. The results showed that optimal volume c...

The effects of ceria and zirconia on the structure-function properties of supported rhodium catalysts (1.6 and 4 wt % Rh/γ-Al2O3) during CO exposure are described. Ceria and zirconia are introduced through two preparation methods: 1) ceria is deposited on γ-Al2O3 from [Ce(acac)3] and rhodium metal is subsequently added, and 2) through the controlled surface modification (CSM) technique, which i...