The title compound, tetra-potassium tetra-[nickel(II)/iron(III)] penta-kis-(orthophosphate), K3.84Ni0.78Fe3.19(PO4)5, has been obtained from a flux. The structure is isotypic with that of K4MgFe3(PO4)5. The three-dimensional framework is built up from (Ni/Fe)O5 trigonal bipyramids with a mixed Fe:Ni occupancy of 0.799 (8):0.196 (10) and isolated PO4 tetra-hedra, one of which is on a general pos...

STUDY OBJECTIVES To compare the results of open myomectomy with those of laparoscopic myomectomy, and to assess complications, surgical results, total hospital cost, and morbidity associated with each procedure. DESIGN Retrospective chart review. SETTING Private practice of one surgeon, and Department of Obstetrics and Gynecology, Rush Medical College, Chicago, Illinois. PATIENTS Ninety-e...

In recent years, a plethora of theoretical carbon allotropes have been proposed, none of which has been experimentally isolated. We discuss here criteria that should be met for a new phase to be potentially experimentally viable. We take as examples Haeckelites, 2D networks of sp(2)-carbon-containing pentagons and heptagons, and "penta-graphene," consisting of a layer of pentagons constructed f...

We introduce an effective tight-binding model to discuss penta-graphene and present an analytical solution. This model only involves the π-orbitals of the sp(2)-hybridized carbon atoms and reproduces the two highest valence bands. By introducing energy-dependent hopping elements, originating from the elimination of the sp(3)-hybridized carbon atoms, also the two lowest conduction bands can be w...

The title tricyclic diene, C(24)H(22)Cl(2), is the product of thermal ring-opening of a corresponding basketane (penta-cyclo-[4.4.0.0(2,5).0(3,8).0(4,7)]deca-ne) derivative. The cyclo-butene ring is planar to within 0.0032 (12) Å and its geometry is normal. The two 4-chloro-phenyl groups are oriented in an approximately face-to-face conformation with a dihedral angle of 44.14 (6)° between them....

The title compound, C(10)H(11)N(2)O(2)P·H(2)O, contains a tetra-coordinate penta-valent P atom. The phosphinate group plays a predominant role in the cohesion of the crystal structure by forming chains along the b axis via inter-molecular C-H⋯O hydrogen bonds. These chains are connected by O-H⋯O and N-H⋯O hydrogen bonding involving the lattice water.