Much has been written of the Columbian exchange, the transfer between New World and Old of people, pathogens, flora and fauna. The biota of two hemispheres, once seemingly irredeemably separated, were interpenetrated, both through accident and through human agency. Part of this exchange involved medicinal and food plants, discovered in the New World and adopted into the Old. This paper examines...

1. Abbasi, M.K., Hina, M., Tahir, M.M., 2011. Effect of Azadirachta indica (neem), sodium thiosulphate and calcium chloride on changes in nitrogen transformations inhibition nitrification soil incubated under laboratory conditions. Chemosphere 82(11), 1629–1635. https://doi.org/10.1016/j.chem.... CrossRef Google Scholar

The oxy-myoglobin (Mb-O2) structure was probed by QM/MM (hybrid quantum mechanical/ molecular mechanical) calculations using DFT/MM to elucidate the effect of the heme propionates and the protein matrix on the chemistry of heme Fe-O2 moiety. On this line, we have probed the role of His97 in various protonation states of the heme propionate-6.

Coherent anti-Stokes Raman scattering (CARS) spectra are reported for flavin adenine dinucleotide (FAD) and glucose oxidase (beta-D-glucose:oxygen 1-oxidoreductase; EC 1.1.3.4), in resonance with the 450 nm flavin absorption band. Several isoalloxazine ring modes were observed (1635, 1584, 1507, 1416, and 1359 cm(-1)). A 12 cm(-1) increase in one component of the 1359 cm(-1) band upon binding t...

Spectral properties of sign symmetric matrices are studied. A criterion for sign symmetry of shifted basic circulant permutation matrices is proven, and is then used to answer the question which complex numbers can serve as eigenvalues of sign symmetric 3 × 3 matrices. The results are applied in the discussion of the eigenvalues of QM -matrices. In particular, it is shown that for every positiv...