BACKGROUND Thermophilic enzymes are often less active than their mesophilic homologues at low temperatures. One hypothesis to explain this observation is that the extra stabilizing interactions increase the rigidity of thermophilic enzymes and hence reduce their activity. Here we employed a thermophilic acylphosphatase from Pyrococcus horikoshii and its homologous mesophilic acylphosphatase fro...

Three distinct procedures for obtaining the effective Gibbs energies of activation from computed a reaction involving multiple reactant-state (RS) and transition-state (TS) conformers are shown to be equivalent. If Boltzmann-weighted average RS TS evaluated, then energy contribution entropy mixing both must also included in order obtain correct value activation. Application solvolytic 4,4′-dime...

the estimate of entropy (sample entropy), has been introduced by vasicek (1976), for the first time. in this paper, we provide an estimate of entropy of order statistics, that is the extention of the entropy estimate. then we present an application of the entropy estimate of order statistics as a test statistic for symmetry of distribution versus skewness. the proposed test has been compared wi...

We train recurrent neural network on a single, long, complex symbolic sequence with positive entropy. Training process is monitored through information theory based performance measures. We show that although the sequence is unpredictable, the network is able to code the sequence topological and statistical structure in recurrent neurons' activation scenarios. Such scenarios can be compactly re...

In the present work, two asymmetric polymer membranes based on polyvinylidene fluoride (PVDF) and polyvinylpyrrolidone (PVP) with chitin and chitosan (as extractive agents) were synthesized through the phase inversion technique. The mechanisms of oriented process for the facilitated extraction of blue P3R dye across the as-prepared membranes were elucidated through different experiments. Furthe...

The objective of this study was to assess the adsorption potential of activated carbon (AC) asan adsorbent for the removal of Murexide (Mu) from aqueous solutions. The influence of variablesparameters including pH, amount of adsorbent, sieve size of adsorbent, temperature and contact timeon Mu removal was studied. Following optimization of variables, the relation between concentrations ofdye re...

Calcium ions have very strong affinity and binds effectively to alizarin red dye during staining of biomaterials. This promotes us to choose calcium hydroxide as a low cost adsorbent for the removal of alizarin red dye. Various parameters such as pH, concentration, dose of adsorbent, time, and temperature have been investigated. In addition, enthalpy, entropy, free energy and activation energy ...

A combined experimental and computational study suggests that a reduction in the entropy of activation in the solid state can lead to the protodeboronation of boronic acids.

In this paper, the two parameter ADK entropy, as a generalized of Re'nyi entropy, is considered and some properties of it, are investigated. We will see that the ADK entropy for continuous random variables is invariant under a location and is not invariant under a scale transformation of the random variable. Furthermore, the joint ADK entropy, conditional ADK entropy, and chain rule of this ent...