Nanoscale manganese oxides within Faujasite zeolite have been synthesized with a simple method and characterized by scanning electron microscopy, X-ray diffraction spectrometry, N(2) adsorption-desorption isotherms, transmission electron microscopy, and atomic absorption spectroscopy. These oxides showed efficient water oxidizing activity in the presence of cerium(IV) ammonium nitrate as a non-...

We report the results of an experimental and theoretical study of propane adsorption on highly oriented pyrolytic graphite. Simulations and experiments were carried out for temperatures from 90 to 110 K and pressures from ultrahigh vacuum up to about 0.5 mTorr. Both simulations and experiments show that propane adsorbs in a layer-by-layer fashion and exhibits continuous growth beyond the second...

The VOx/LUS-1 nanoporous silica synthesis and characterized by XRD, Nitrogen adsorption–desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various (methanol, acetone, acetic acid, acetonitryl) solvents.

Department of Chemistry and the Inter Northwestern University, 2145 Sheridan Ro E-mail: [email protected] Department of Chemical & Biological Eng Sheridan Road, Evanston, IL, 60208, USA † Electronic supplementary information ( the synthesis of hierarchically porous orga (gas adsorption–desorption isotherms, por and density data). Detailed procedures calculation of diffusion constants. See DO...

Adsorption of gases in porous adsorbents such as coal and shale generally exhibits the phenomenon hysteresis. Most previous studies on desorption hysteresis were conducted via experimental tests. However, few theoretical models that represent adsorption–desorption sorbents are available. To address this issue, work develops a new model for describing adsorption isotherms with Particularly, ener...

Permeable reactive barriers (PRBs), a new cost effective technology for the remediation of contaminated groundwater, have rarely been considered for PAH contamination. We evaluated three candidate matrices (activated carbon (AC), pouzzolana coated (PzF) or not (Pz) with heavy fuel oil) for phenanthrene (PHE) sorption capacity and the biodegradation of adsorbed PHE. Adsorption-desorption batch e...

This paper examines the effects of multicycles desorption/adsorption on water isotherms a typical cement–bentonite mixture. These were evaluated over relative humidity (RH) range 90% and 0.3%. study shows that, after first adsorption–desorption cycle, subsequent cycle shifted isotherm curves upward, particularly at RH < 70%, with high degree hysteresis. In contrast, > slightly downward lo...

The rapid increase in the use of engineered nanoparticles [ENPs] has resulted in an increasing concern over the potential impacts of ENPs on the environmental and human health. ENPs tend to adsorb a large variety of toxic chemicals when they are emitted into the environment, which may enhance the toxicity of ENPs and/or adsorbed chemicals. The study was aimed to investigate the adsorption and d...

A zirconium sulfate-surfactant micelle mesostructure (ZS) was synthesized to investigate its capacity for phosphate removal from water. Its phosphate adsorption kinetics, the effect of pH and interfering anions, adsorption isotherm, desorption capacity, and reusability were investigated. The adsorption isotherms could be described by the Langmuir model. The ZS was an effective adsorbent for pho...