Internal cation mobility ratios in molten (Ca, Ba)Cl2 have been measured by the Klemm method for xBa (mole fraction of barium chloride) = 0.25 0.51 at 973 K and xBa = 0 0.61 at 1073 K. From these and available data on the densities and conductivities the internal cation mobilities b have been calculated, assuming additivity of the molar volume. Although bCa in pure CaCl2 is greater than bBa in ...

Electrode potential measurements have been applied to study electrical characteristics like transport numbers, permselectivity & fixed charge density of ion-exchange membranes. Membrane potential measurements were made across zirconium phosphotungstate cation-exchange membrane maintained at 27◦C, using halide salts of alkali & alkaline earth metals as electrolytes. The effect of concentration o...

Abstract Glycerol can be converted to propylene glycol via metal and base catalyzed hydrogenolysis. The nature of the has a profound influence on outcome reaction. We have tested range alkaline (LiOH, NaOH CsOH) earth (Mg(OH) 2 , Ca(OH) Sr(OH) Ba(OH) ) hydroxides in combination with Pt/C. data reveal that exhibit much higher activity improved selectivity. DFT calculations confirm coordination r...

Anion exchange membranes (AEMs) find widespread applications as an electrolyte and/or electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and electrolyzers. AEMs exhibit poor stability in alkaline media; their degradation is induced by the hydroxide ion, a potent nucleophile. We have used 2D NMR techniques to investigate polymer backbone stability (as opposed t...

the acute toxicity of salts of alkali and alkaline earth metals, such as sodium (na), potassium (k), calcium (ca) and magnesium (mg) were studied on the egg and larval stages of indian major carp labeo rohita (hamilton). the acute toxicity experiments were conducted followed by the range finding bioassay tests. the experiments were conducted in triplicates. the cumulative percentage of dead or ...

Investigating the release characteristics of alkali and alkaline earth metallic species (AAEMs) is of potential interest because of AAEM's possible useful service as catalysts in biomass thermal conversion. In this study, three kinds of typical Chinese biomass were selected to pyrolyse and their chars were subsequently steam gasified in a designed quartz fixed-bed reactor to investigate the rel...

It is known that the electro-transport and magnetism of perovskite alkaline-earth ruthenate oxides are sensitive to the lattice distortion associated with the A-site cation size. Orthorhombic CaRuO3 and cubic BaRuO3 exhibit distinctly different electro-transport and magnetic properties from orthorhombic SrRuO3. It has been suggested that SrRuO3 can be robust against some intrinsic/external pert...

The influence of the nature of the cation on the interaction of the silicoaluminophosphate SAPO-34 with small hydrocarbons (ethane, ethylene, acetylene, propane, propylene) is investigated using periodic density-functional theory calculations including a semi-empirical dispersion correction (DFT-D). Initial calculations are used to evaluate which of the guest-accessible cation sites in the chab...