Synthesis of (4',5'-diaza-9'-fluorene)-spiro-5-hydantoin: The paper presents a method for synthesis of (4',5'-diaza-9'-fluorene)-spiro-5-hydantoin. The newly obtained compound was synthesized by a treatment of 4,5-diazafluoren-9-one with sodium cyanide, ammonium carbonate, ethanol and ammonium hydroxide at high pressure and high temperature. The structure of (4',5'-diaza-9'-fluorene)-spiro-5-hy...

Fresh egg waffles are continuously baked in tunnel baking ovens in industrial scale. Waffles that partly or fully stick to the baking plates cause significant product loss and increased costs. The aim of this study was, therefore, to investigate the effect of different recipe ingredients on the sticking behavior of waffles. In this second part, ingredients investigated were different leavening ...

Band theoretical results are presented on UO2CO3, based on computations within the density functional theory. The equation of state is obtained with equilibrium lattice properties in agreement with experiment. For isotropic volume change the bulk modulus amounts to 176 GPa. A higher value for anisotropic compression along the linear uranyl characterizes its incompressibility. The electronic ban...

Sulfate-rich acid waters produced by oxidation of sulfide minerals enhance U mobility around U ores and U-bearing radioactive waste. Upon evaporation, several secondary uranyl minerals, including many uranyl sulfates, precipitate from these waters. The zippeite-group of minerals is one of the most common and diverse in such settings. To decipher the nature and crystal chemistry of the zippeite-...

The interaction of reagent grade strontium sulphate and celestine concentrate with aqueous solutions of oxalic acid, sodium oxalate and ammonium oxalate for the production of strontium carbonate were investigated for different oxalate compound:SrSO4 mole ratios and reaction times using x-ray diffraction analysis and dissolution tests. Under the same experimental conditions, it was found that aq...

The potentiometric response properties of ammonium-, carbonate-, and proton-selective electrodes prepared by incorporating appropriate neutral carriers within novel asymmetric cellulose acetate membranes are reported. The membranes are formed by first casting a thin layer of cellulose triacetate without carrier, hydrolyzing one side of this film with base, and then on the other side casting a s...

The physicochemical characterization of uranium(V1) in seawater is described on the basis of species distribution calculations and experiments using polarography and spectrophotometry in artificial seawater at elevated uranium concentrations. Various dissolved uranium(W) species are identified under different conditions of pH and carbonate concentration. Below pH 4, the hydrated uranyl ion is p...

Column experiments were conducted to investigate U(VI) desorption and sorption kinetics in a sand-textured, U(VI)-contaminated (22.7 micromol kg(-1)) capillary fringe sediment from the U.S. Department of Energy (DOE) Hanford site. Saturated column experiments were performed under mildly alkaline conditions representative of the Hanford site where uranyl-carbonate and calcium-uranyl-carbonate co...