Polycyclic aromatic hydrocarbons in three sections of a dated sediment core from Buzzards Bay, Massachusetts, have been analyzed by gas chromatographic spectrometry. This historical information suggests that sedimentary polycyclic aromatic hydrocarbons, at least at this location, result primarily from the anthropogenic combustion of fossil fuels.

Effects of individual petroleum hydrocarbons on the luminescence inhibition of Vibrio fischeri were evaluated according to a standard protocol to develop a quantitative structure-activity relationship and identify the apparent toxicity cutoff. Eighteen aromatic hydrocarbons, including benzene and its derivatives and polycyclic aromatic hydrocarbons (PAHs), were chosen as model compounds with th...

A method for the qualitative analysis of aromatic hydrocarbons in air and their various urinary metabolites is presented. The air was sampled in charcoal tubes and extracted with carbon disulfide. The hydrocarbons were identified as being aliphatic hydrocarbons (C(9)-C(19)), aromatic hydrocarbons and heterocyclic compounds. The urinary metabolites after enzymatic hydrolysis were analyzed by sol...

Clar's aromatic sextet theory provides a good means to describe the aromaticity of benzenoid hydrocarbons, which was mainly based on experimental observations. Clar defined sextet pattern and Clar number of benzenoid hydrocarbons, and he observed that for isomeric benzenoid hydrocarbons, when Clar number increases the absorption bands shift to shorter wavelength, and the stability of these isom...

in this study, the degradation potential of five polycyclic aromatic hydrocarbons (pahs) by aerobic mixed bacterial cultures was investigated. microorganisms were isolated from hydrocarbon contaminated soils of shadegan wetland located in southwest of iran. the degradation experiments were conducted in liquid cultures. pah or pahs concentration was 100 mg/l at the beginning of degradation exper...

in this study, oxic and anoxic microcosms were constructed with aquifer sediment collected from the vicinity of a municipal solid waste composting site.phenanthrene was used as a model pah compound. the changes of bacterial and archaeal communities in microcosms were characterized with terminal restriction fragment length polymorphism. 16s rrna gene clone library analysis was also used to inves...

a fast and simple modified quechers (quick, easy, cheap, rugged and safe) extraction method based on spiked calibration curves and direct sample introduction was developed for determination of benzo[a]pyrene (bap) in bread by gas chromatography-mass spectrometry single quadrupole selected ion monitoring (gc/ms-sq-sim). sample preparation includes extraction of bap into acetone followed by clean...

aims of the study: endometriosis is a prevalent gynecologic disorder in young women at reproductiveage but the underlying risk factors have not identified yet in iran and other neighboringcountries. persistent exposure to environmental endocrine disrupting chemicals (edcs) in particulardioxins, pahs and polychlorinated biphenyls (pcbs) with xenoestrogenic potentials have beenhypothesized in the...

The mid-infrared (5–16 μm) spectral energy distribution for an individual quiescent molecular cloud in the Small Magellanic Cloud (SMC) was observed using ISOCAM. The spectrum is dominated by broad emission bands at 6.2, 7.7, and 11.3 μm, with weaker bands at 8.6 and 12.7 μm. As these are the same bands, with similar shape and relative strengths, as observed in the ISM of our Galaxy, the same c...