This work reports the applicability of a voltammetric sensor array able to quantify the content of 2,4-dinitrophenol, 4-nitrophenol, and picric acid in artificial samples using the electronic tongue (ET) principles. The ET is based on cyclic voltammetry signals, obtained from an array of metal disk electrodes and a graphite epoxy composite electrode, compressed using discrete wavelet transform ...

A three-sensor array consisting of a graphite-epoxy composite electrode (GEC), 4-carboxybenzo-18-crown-6-GEC and 4carboxybenzo-15-crown-5-GEC was employed for the simultaneous determination of Cd(II), Pb(II) and Hg(II) by differential pulse anodic stripping voltammetry (DPASV). Sensors were firstly studied for the determination of Hg(II); secondly, peak current responses confirmed that all sens...

We demonstrate that chain polymerization of molecules can be initiated by stimulating a thin molecular film with a scanning tunneling microscope (STM) tip, so that a conjugated polymer nanowire can be created at designated positions. The demonstration has been presented for a self-ordered monomolecular layer of diacetylene compound adsorbed on a graphite surface. By stimulating the molecular la...

In order to compare and evaluate the atomization process occurring in several types of graphite furnaces for atomic absorption spectrometry, the authors estimated temporal variations in the gas temperature by using a two-line method under the assumption of a Bolzmann distribution. The atomization furnaces employed were a graphite tube, a graphite tube coated with pyrolitic carbon, a graphite tu...

low water-wettability and oxidation resistance of graphite have limited its application in carbon containing refractory castables. the aims of this study were improvement of water-wettability and the oxidation resistance of natural flaky graphite by applying an oxide coating on its surface. to develop the coating, magnesium aluminate spinel sol was formulated via a citrate-nitrate route and gra...

production of fe-c alloy powders by mechanical alloying was studied. fe and graphite elemental powdermixtures containing 0.8 and 1.5wt.% graphite were mechanically alloyed using a planetary ball mill. thestructural changes of powder particles during mechanical alloying were studied by x-ray diffractometery,scanning electron microscopy and microhardness measurements. for both compositions, mecha...

The present paper deals with the design of experimental work matrices for two groups of experiments by using Response surface methodology (RSM). The first EDM group was dealt with the use of kerosene dielectric alone, while the second was treated by adding the graphite micro powders mixing to dielectric fluid (PMEDM). The total heat flux generated and fatigue lives after EDM and PMEDM models we...

Graphite or plumbago is a crystalline form of carbon which occurs in nature as soft black masses or, less commonly, as crystals in igneous rocks: this natural graphite contains varying proportions of other minerals. Graphite is also made artificially from coke, and the best preparations of this kind are nearly pure carbon. This paper will deal with some of the effects of natural graphite, and t...