While several databases with Raman spectra of interest to silver corrosion have been published already, we present a catalogue of Raman spectra of silver compounds, which can be found on corroded silver and silver alloy objects, i.e. not only concerning archaeological and artistic works but all kind of silver items exposed to the atmosphere. The collected Raman spectra of these highly pure (>99...

* Corresponding author. Tel: 34 1 3944348; Fax: 34 1 3944357 E-mail: [email protected] ABSTRACT X-ray photoelectron spectroscopy (XPS) was used in order to investigate the correlation between the surface chemistry and the atmospheric corrosion of AZ31, AZ80 and AZ91D magnesium alloys exposed to 98% relative humidity at 50oC. Commercially pure magnesium, used as the reference material, reveale...

Tapping mode atomic force microscopy (TM-AFM) was used for the investigation of the early stages of atmospheric corrosion of pure copper and pure iron. The information obtained by this method is the change of the topography of the sample surfaces with emphasis on the shape and lateral distribution of the corrosion products grown within the first 1300 min of weathering. Investigations were carri...

The role of sodium chloride (NaCl) particles and ammonium sulfate ((NH4)2SO4) particles on the initial atmospheric corrosion of copper and zinc was investigated under in situ and ex situ conditions using microgravimetry, FTIR spectroscopy, ion chromatography, scanning electron microscopy with x-ray microanalysis and the scanning Kelvin probe. For the first time, in situ infrared spectra were co...

One of the heaviest problems of reinforced concrete structures consists in the steel armature corrosion. The steel armature condition affects, above all, the properties of horizontal structures. It is to be noted that the corrosion process itself may not be observable from the outside in many cases. This is why studies of non-destructive methods allowing the researchers to detect the degree of ...

Atmospheric corrosion occurs under alternate cycles in presence and absence of an electrolyte layer, the severity of corrosion processes that occur onto the metallic surface depends largely on the corrosive environment to which the material is exposed. Whereas the corrosive phenomena occur in the presence of the electrolyte, in this work the effect of the depth of the solution layer on the elec...

The evolution of akaganeite in rust layers strongly impacts the atmospheric corrosion behavior of steel during long-term exposure; however, the factors affecting the evolution of akaganeite and its mechanism of formation are vague. In this work, wet-dry cyclic corrosion tests were conducted to simulate long-term exposure. Quantitative X-ray diffraction analysis was employed to analyze variation...

Air pollutants such as carbon dioxide play an important role in atmospheric corrosion processes and therefore in the degradation reactions occurring on metal surfaces exposed to an ambient atmosphere. It is known from macroscopic studies that ultraviolet (UV) light influences these surface reactions with respect to the reaction rate and the product formation itself even though the exact mechani...