The photodegradation of the azobenzene chromophore DR1 {4-[N-ethyl-N-(2-hydroxyethyl)amino]-4(?)-nitroazobenzene]} incorporated as a side chain or as a guest in a poly(methyl) methacrylate host has been evaluated as a function of wavelength, temperature, and the atmospheric environment. The effects of these variables on the lifetime of DR1-based electro-optic devices is quantified.

[1] We calculate the global mean atmospheric lifetime of elemental mercury (Hg) against oxidation by atomic bromine (Br) in the troposphere by combining recent kinetic data for the Hg-Br system with modeled global concentrations of tropospheric Br. We obtain a lifetime of 0.5–1.7 years based on the range of kinetic data, implying that oxidation of Hg by Br is a major, and possibly dominant, glo...

Recent experimental findings indicate that HSO5 radicals may play a key role in the nucleation of atmospheric SO2 oxidation products. HSO5 radicals are metastable intermediates formed in the SO2 oxidation process, and their stability and lifetime are, at present, highly uncertain. Previous high-level computational studies have predicted rather low stabilities for HSO5 with respect to dissociati...

Atmospheric emissions of carbon tetrachloride (CCl4) are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so called "mystery of CCl4", the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl4 atmospheric con...

in the last decade, decrease of the wear rate, increase in the axel load, and the velocity of the trains have changed the main damage mechanism of railway wheels from wear to rolling contact fatigue (rcf). rcf may lead to surface and subsurface cracks. the interaction between wear and rcf, removes the surface cracks, but the subsurface crack propagate gradually, and may lead to deeper and more ...

Over the last few years a theoretical treatment for the weak decays of heavy-flavour hadrons has been developed that is genuinely based on QCD. Its methodology is described as it applies to total lifetimes, and the underlying theoretical issues are discussed. Theoretical expectations are compared with present data. One discrepancy emerges: the beauty baryon lifetime appears to be significantly ...

Hydration directly affects the mobility, thermodynamic properties, lifetime and nucleation rates of atmospheric ions. In the present study, the role of ammonia on the formation of hydrogen bonded complexes of the common atmospheric hydrogensulfate (HSO(4) (-)) ion with water has been investigated using the Density Functional Theory (DFT). Our findings rule out the stabilizing effect of ammonia ...

Despite the fact that the occurrence of polycyclic aromatic hydrocarbons (PAHs) in the atmospheric environment has been studied for decades the photochemistry, deposition and, consequently, the long-range transport potential (LRTP) are not well understood. The reason is gas-particle partitioning (GPP) in the aerosol, its sensitivity to temperature and particulate phase composition, and sampling...

Nitrous oxide (N2O) is one of the top three greenhouse gases whose emissions may be brought under control through the Framework Convention on Climate Change. Current understanding of its global budget, including the balance of natural and anthropogenic sources, is largely based on the atmospheric losses calculated with chemical models. A representative one-dimensional model used here describes ...