نتایج جستجو برای: auto catalysis
تعداد نتایج: 54064 فیلتر نتایج به سال:
Vahid Khakyzadeh was born in Hamedan, Iran. He received his B.S. degree (Pure Chemistry) and M.S. degree (Organic Chemistry) from Bu-Ali Sina University, Hamedan, Iran, at 2008, 2010 respectively under supervision of professor Mohammad Ali Zolfigol. He is currently working on his Ph. D. under the supervision of professor Mohammad Ali Zolfigol in organic chemistry. Among his recent awards, Vahid...
Decreasing supplies of high quality crude oil and increasing demand for high quality distillates have motivated the interest in converting natural gas to liquid fuels, especially with the present boom in natural gas proven reserves. Nevertheless, one major issue is the curtailment of costs incurred in producing synthesis gas from natural gas, which account for approximately 60% of the costs use...
The ability of systems of molecular reactions to be simultaneously autocatalylic and sustained by some ambient 'food source' of simple molecules may have been an essential step in the origin of life. In this paper we first describe a polynomial-time algorithm that determines whether any given set of molecules, reactions and catalysations contains a subsystem that is both autocatalytic and able ...
A convenient carbonylative approach to 2-oxazolidinone derivatives carried out using an ionic liquid (1-ethyl-3-methylimidazolium ethyl sulfate, EmimEtSO₄) as the solvent is presented. It is based on the sequential concatenation of two catalytic cycles, both catalyzed by the same metal species (auto-tandem catalysis): the first cycle corresponds to the oxidative monoaminocarbonylation of the tr...
A salient characteristic of the prion diseases--including Creutzfeldt-Jakob disease and bovine spongiform encephalopathy in cattle--is an extended asymptomatic incubation period followed by a rapid and often fatal clinical phase. We present a kinetic model of progression of infection based upon the existence of a bottleneck in the natural protein pathways within the cell. The model can reconcil...
Abstract: Stochastic differential equations provide a useful means of introducing stochasticity into models across a broad range of systems from chemistry to population biology. However, in many applications the resulting equations have so far proved intractable to direct analytical solution. Numerical approximations, such as the Euler scheme, are therefore a vital tool in exploring model behav...
Meysam Yarie was born in 1987 in Malayer, Hamedan, Iran. He received his B.Sc. in Applied Chemistry (2010) from Malek-Ashtar University of Technology and M.Sc. in Organic Chemistry (2012) from Kurdistan University under the supervision of Dr. Kamal Amani. He is currently working towards his Ph.D. under the supervision of Professor Mohammad Ali Zolfigol. His research interest is catalysis, inclu...
In this work, benzyl alcohol was obtained in 96% excellent yield by hydrolysis of benzyl chloride catalyzedby the recyclable temperature-dependant phase-separation system that comprised the ionic liquid PEG1000-DAIL[BF4], toluene and ferric sulfate under homogeneous catalysis in aqueous media. This novel methodnot only enhanced the yield, but also made the operating units easy workup. The catal...
Selective transformation of 2-propargylthio-6-methyl-pyrimidin-4(1H)On e (2) to 3,5-dimethyl-7H-thiazolo [3,2-a] pyrimidin-7-one (3) is performed under the conditionof base catalysis . For elucidation of structure, palladium catalyzed cyclization reaction of (2) was carried out and the structures of the products were assigned (5) and (6). These compounds underwent isomerization to (3) and (4...
in multi-step organic syntheses, the protection and deprotection of tetrahydropyranyl (thp) ethers is one of the most frequently used methods. over the years, different methods have been used from various catalytic systems for the protection of hydroxyl groups as thp ethers and their deprotection. herein we have reported that various alcohols and phenols have been efficiently converted to the c...
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