In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the mol-ecules are linked into a one-dimen...

The six-membered thio-pyran ring in the title compound, C(24)H(20)S, adopts a flattened boat conformation, with the S atom displaced by 0.273 (2) Å and the 3-methyl-ene C atom by 0.294 (3) Å from the plane of the other four sp(2)-hydridized C atoms. The methyl group on the methyl-ene carbon lies in a axial position with the phenyl equatorial.

In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino-bis-(propyl-amine) and salicyl-aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter-molecular hydrogen bonds with...

In the title compound, C22H26N2O3, the piperidine ring exhibits a chair conformation. The phenyl rings attached to the piperidine at the 2- and 6-positions have axial orientations. These rings make a dihedral angle of 49.75 (11)°. The amino-oxy acetate group attached at the 4-position has an equatorial orientation. In the crystal, inversion dimers linked by pairs of C-H⋯π inter-actions occur.

In the title compound, C(24)H(27)NO(10)S(2), derived from l-sorbofuran-ose, the fused five-membered rings display envelope conformations. The two tosyl-ate branches are in equatorial positions with respect to the furan-ose ring, while the hydr-oxy group is in the axial position. In the crystal structure, the hydr-oxy group is involved in inter-molecular O-H⋯O hydrogen bonds, linking mol-ecules ...

The new complexes [Rh(Me)(trop3P)] (2) and [Rh(Ph)(trop3P)] (3) (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) were synthesised by addition of organolithium reagents (MeLi PhLi) to the parent pentacoordinated chloride complex [RhCl(trop3P)]. compounds have a trigonal bipyramidal structure with olefin-only ligands in equatorial position methyl or phenyl substituent axial position. Oxidation 2 3 leads ...

In the title mol-ecule, C(27)H(24)N(2)O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bis-ectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bis-ectional and axial orientations, respectively, and make a dihedral angle of 75.27 (10)°. The phenyl-acetonitrile group at position 4 has an equatorial orientation...

The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2'-[(3-aza-pentane-1,5-diylbis(nitrilo-methyl-idyne)]dipyrrole and 4-Mepy is 4-methyl-pyridine, contains a penta-dentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial position...

In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of ...

In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three benzene rings make dihedral angles of 87.83 (17),...