Pseudoazurins are small type 1 copper proteins that are involved in the flow of electrons between various electron donors and acceptors in the bacterial periplasm, mostly under denitrifying conditions. The previously determined structure of Paracoccus pantotrophus pseudoazurin in the oxidized form was improved to a nominal resolution of 1.4 A, with R and R(free) values of 0.188 and 0.206, respe...

The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF6, [omim]BF4 and [hmi...

As part of our ongoing project that aims at the optimum characterization of the electronic structure of the blue-copper site of azurin from Pseudomonas aeruginosa, we present the complete hyperfine tensors of the protons bound to the Cbeta atom of the copper-bound cysteine 112. These tensors have been obtained from a 95 GHz pulsed electron-nuclear double resonance study of a single crystal of t...

OF DOCTORAL DISSERTATION HELSINKI UNIVERSITY OF TECHNOLOGY P.O. BOX 1000, FI-02015 TKK http://www.tkk.fi Author Tiina Marjatta Komulainen Name of the dissertation Novel modeling and control approach for performance improvement of an industrial copper solvent extraction process Manuscript submitted 21.5.2007 Manuscript revised 9.10.2007 Date of the defence 30.11.2007 Monograph Article dissertati...

Optical rotatory dispersion and circular dichroism spectra of the Pseudomonas blue protein and lactase B from Polyporus versicolor are presented from 190 to 700 mp. Circular dichroism spectra of both proteins show six ellipticity bands above 300 rnp associated with the copper chromophore, indicating more transitions to be present in these copper protein complexes than the three parity-forbidden...

the aim of this study was to identify the effect of spermine and salicylic acid on several growth parameters, such as shoot length, shoot fresh and dry weights, amount of protein and carbohydrate, of badami and qazvini pistachio cultivated variety under copper stress. the experiment design was completely randomized with three replicates per treatment and four levels of copper (o.5, 30, 45, 60 µ...

Halocyanin, a small blue copper protein, was isolated from the haloalkaliphilic archaeon Natronobacterium pharaonis. The NH2 terminus was not accessible to Edman degradation. About 70% of the amino acid sequence was determined by protein sequence analysis. The sequence information of two peptides was used for cloning and sequencing the halocyanin gene (hcy). The open reading frame codes for 489...

Copper in bile has been shown by electrophoresis to occur neither as free ions nor complexed to protein but to be associated with a component of the micellar complexes of bile. Solvent fractionation studies suggest that the bile salt components of the lecithin-bile salt complexes are the active binding agents. The effects of specific bile salts on the behaviour of copper during electrophoresis ...

A combination of spectroscopies and density functional theory calculations indicate that there are large temperature-dependent absorption spectral changes present in green nitrite reductases (NiRs) due to a thermodynamic equilibrium between a green and a blue type 1 (T1) copper site. The axial methionine (Met) ligand is unconstrained in the oxidized NiRs, which results in an enthalpically favor...