Protic ionic liquids (PILs) are currently being shown to be as interesting and valuable to chemical manipulations as the well-known aprotic ionic liquids (APIL). PILs have the additional advantage that the proton activity (PA) can be adjusted by the choice of Bronsted base and Bronsted acid used in their formation. In the absence of solvent, the PA plays the role of pH in ordinary solutions. Pr...

AB S TRACT: Montmorillonites ion-exchanged with Li +, Na +, K § Ca 2+, Mg 2+ and Ni 2+ and acidic clay were used as catalysts for the polymerization of a cyclic siloxane monomer, 2,4,6,8tetramethylcyclotetrasiloxane. Montmorillonites with Ni 2+ and Mg 2+ in the interlayer, and acidic clay exhibit a greater ability for siloxane polymerization in both yield and mean molecular weight of products t...

In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods tested in the oxidation sulfur- nitrogenous-containing compounds H2O2. An increase amount heteropolyacid (HPA) leads to non-linear change acidity, degree removal sulfur-containing correlates with concentrat...

A series of metal ion (M = Sn2+, Fe3+, Ni2+, Co2+, Ag+, Cu2+) exchanged tungstophosphoric acid (H3PW12O40; TPA) catalysts with tunable Bronsted/Lewis acidity were synthesized and exploited for the oxidation benzyl alcohol (BzOH) to benzaldehyde (BzH) using hydrogen peroxide (H2O2) as oxidant. The structure these M-TPA composite salts was also characterized by Fourier transform infrared spectros...

One of the most trending topics in catalysis recently is use renewable sources and/or non-waste technologies to generate products with high added value. That why, present review resumes advances catalyst design for biomass chemical valorization. The variety involved reactions and functionality obtained molecules requires multifunctional able increase efficiency selectivity selected process. glu...

The reaction of levulinic acid production from glucose has a stage that requires high temperature and activation energy so in this catalyst is needed. required must have lewis site bronsted the acidity very influential for successful levulonic acid. Silica nickel phosphate catalysts sites Ni metal phosphoric silica groups. was measured using pyridine ammonia adsorption method center strength TG...

This study primarily addresses the development of dynamic, selective and economical metal–acid (bifunctional) catalysts for one-pot menthol production by citral hydrogenation. Specifically, various metals such as Pd, Pt, Ni, Cs Sn were doped over alumina support. Additionally, bifunctional composite also prepared with impregnation heteropoly acids Pd precursors Analytical techniques (e.g., BET,...

Objective: The coordination and electrochemistry-related effects uses of piperidine dithiocarbamate (pipdtc) piperazine (pzdtc) are the main topics this article. Method: An environment friendly electroless bath was created using a very small amount biodegradable methanesulphonic bronsted acid, Glyoxylic acid as reducing agent, Xylitol non-toxic natural polyhydroxylic complexing agent potassium ...