The reactions of [(thf)2TiCl4] with sodiated 2,2’-bis[2-hydroxy-3,5-di(tert-butyl)benzylideneamino]-1,1’-biphenyl (1 a) and 2,2’-bis[2-hydroxy-3,5-di(tert-butyl)benzylideneamino]-4,4’-dimethyl-1,1’-biphenyl b) yield the corresponding Ti complexes 2 a b. Similarly, 1 reacts [(thf)2ZrCl4] to Zr derivative 3. For a, mixture cis-β trans isomers were observed in solution whereas congener exclusively...

Starch based materials are attractive bio-based alternative to fully synthetic polymers. Native starch has however limited thermoprocessability and properties must be modified. In order improve the of starch-graft-poly(butyl-acrylate-co-styrene) copolymers via a process as green possible, we report herein new method for dual functionalization polysaccharide one pot step reaction in aqueous medi...

Injection of N-butyl-2-cyanoacrylate has been used successfully for treatment of gastric variceal bleeding. Bacteremia after injection of N-butyl-2-cyanoacrylate is well known, however, the method for diagnosis of infected endovascular injected material has remained uncertain. This is the first case reporting use of F-18 FDG PET/CT in detection of the source of infection after control of endosc...

Butyl stearate as a phase change material was microencapsulated within melamine-formaldehyde resin using emulsion polymerization. Morphology and thermal specification of produced microcapsules were studied by Fourier transform infrared spectroscopy, FT-IR, scanning electron microscopy, SEM, and Differential scanning calorimetry analysis, DSC. FT-IR spectra validated the existence of the butyl s...

BACKGROUND Patients with acute renal colic usually require immediate diagnosis and treatment. In this clinical trial analgesic effect of hyoscine N-butyl bromide and desmopressin combination in comparison with hyoscine N-butyl bromide alone in patients with acute renal colic induced by urinary stones was assessed. METHODS The study included 114 patients randomly allocated in two groups (A and...