We unveil a unique kinetic driven separation material for selectively removing linear paraffins from iso-paraffins via a molecular sieving mechanism. Subsequent carbonization and thermal treatment of CD-MOF-2, the cyclodextrin metal-organic framework, afforded a carbon molecular sieve with a uniform and reduced pore size of ca. 5.0 Å, and it exhibited highly selective kinetic separation of n-bu...

To improve the CO2/N2 separation performance, mixed-matrix carbon molecular sieve membranes (mixed-matrix CMSMs) were fabricated and tested. Two carbon-based fillers, graphene oxide (GO) activated (YP-50F), separately incorporated into two polymer precursors (Matrimid® 5218 ODPA-TMPDA), resulting CMSMs demonstrated improved CO2 permeability. The improvement afforded by YP-50F was more substanti...

An innovative concept is proposed to recover ammonia from industrial wastewater using a molecular sieve silica membrane in pervaporation (PV), benchmarked against vacuum membrane distillation (VMD). Cobalt and iron doped molecular sieve silica-based ceramic membranes were evaluated based on the ammonia concentration factor downstream and long-term performance. A modified low-temperature membran...

We have performed first-principles density functional theory calculations, incorporated with van der Waals interactions, to study CO2 adsorption and diffusion in nanoporous solid – OMS2 (Octahedral Molecular Sieve). We found the charge, type, and mobility of a cation, accommodated in a porous OMS-2 material for structural stability, can affect not only the OMS-2 structural features but also CO2...

This work shows mixed matrix inorganic membranes prepared by the vacuum-assisted impregnation method, where phenolic resin precursors filled the pore of α-alumina substrates. Upon carbonisation, the phenolic resin decomposed into several fragments derived from the backbone of the resin matrix. The final stages of decomposition (>650 °C) led to a formation of carbon molecular sieve (CMS) structu...

Carbon molecular sieves were prepared from petroleum coke by chemical activation. The effects of activation temperature, holding time, preliminary treatments and activated agent ratio on surface area, pore structure of the carbon molecular sieves produced in our lab were investigated. The specific surface area and average pore size of the carbon are obviously increased with increasing use of ac...

We studied the metabolism of A14l-insulin in intact human fibroblasts using high performance liquid chromatography (HPLC) to detect and separate its early degradation products. The high resolving power of HPLC enabled us to separate what has been considered "intact insulin" by Sephadex G-50 chromatography or TCA precipitability into two additional peaks that had decreased biochemical properties...