In comparison with the amount of study undertaken on end-Permian mass extinction, preceding Guadalupian extinction has received little investigation, even though it marks a significant biotic turnover associated global environmental changes. During earlier event, reef carbonate production shut down and was replaced by siliceous, mud-rich deposits (SRDs) in South China. However, changes platform...

A well-preserved Cambrian section in the Zanskar Valley of northern India has previously been interpreted to record the transition from a passive to an active tectonic margin related to Cambrian–Ordovician orogenesis. This interpretation has been used to support the tectonostratigraphic interpretation of other successions across the Tethyan Himalaya. Our detailed paleoenvironmental analysis sig...

Nacre-mimetic materials are of great interest, but difficult to synthesize, because they require the ordering of organic and inorganic materials on several length scales. Here we introduce peptoid nanosheets as a versatile two-dimensional platform to develop nacre mimetic materials. Free-floating zwitterionic nanosheets were mineralized with thin films of amorphous calcium carbonate (of 2-20 nm...

We demonstrate a modular "click"-based functionalization scheme that allows inexpensive conductive diamond samples to serve as an ultrastable platform for surface-tethered electrochemically active molecules stable out to ∼1.3 V vs Ag/AgCl. We have cycled surface-tethered Ru(tpy)(2) to this potential more than 1 million times with little or no degradation in propylene carbonate and only slightly...

Several positive carbon isotope excursions in Lower Paleozoic rocks, including the prominent Upper Cambrian Steptoean Positive Carbon Isotope Excursion (SPICE), are thought to reflect intermittent perturbations in the hydrosphere-biosphere system. Models explaining these secular changes are abundant, but the synchronicity and regional variation of the isotope signals are not well understood. Ex...