نتایج جستجو برای: carbothermal

تعداد نتایج: 304  

Journal: :Nanoscale 2015
Tao Yang Xiwang Chang Junhong Chen Kuo-Chih Chou Xinmei Hou

B-doped 3C-SiC nanowires have been synthesized via a facile and simple carbothermal reduction method at 1500 °C for 2 h in a flowing purified argon atmosphere. The obtained nanowires possess a single crystalline and finned microstructure with fins about 100-200 nm in diameter and 10-20 nm in thickness. The diameter of the inner core stem is about 80 nm on average. Due to the smaller band gap, t...

2011
Ayan Kar Ke-Bin Low Michael Oye Michael A Stroscio Mitra Dutta Alan Nicholls M Meyyappan

ZnO nanowire nucleation mechanism and initial stages of nanowire growth using the carbothermal reduction technique are studied confirming the involvement of the catalyst at the tip in the growth process. Role of the Au catalyst is further confirmed when the tapering observed in the nanowires can be explained by the change in the shape of the catalyst causing a variation of the contact area at t...

2011
Chunyu Ma Zhihua Zhou Hao Wei Zhi Yang Zhiming Wang Yafei Zhang

ZnO nanowires are a promising nanomaterial for applications in the fields of photocatalysis, nano-optoelectronics, and reinforced composite materials. However, the challenge of producing large-scale ZnO nanowires has stunted the development and practical utilization of ZnO nanowires. In this study, a modified carbothermal reduction method for preparing large-scale ZnO nanowires in less than 5 m...

2018
Carine E. Chan-Thaw Alberto Villa

Transition metal carbides have been utilized as an alternative catalyst to expensive noble metals for the conversion of biomass. Tungsten and molybdenum carbides have been shown to be effective catalysts for hydrogenation, hydrodeoxygenation and isomerization reactions. The satisfactory activities of these metal carbides and their low costs, compared with noble metals, make them appealing alter...

2017
Hamid Esfahani Rajan Jose Seeram Ramakrishna

Ceramic nanofibers (NFs) have recently been developed for advanced applications due to their unique properties. In this article, we review developments in electrospun ceramic NFs with regard to their fabrication process, properties, and applications. We find that surface activity of electrospun ceramic NFs is improved by post pyrolysis, hydrothermal, and carbothermal processes. Also, when combi...

2017
Tomohiro Takeuchi Jun Fukushima Hirotsugu Takizawa Giancarlo Cravotto

The polymer electrolyte fuel cell (PEFC) is an attractive power generation method from the perspective of environmental protection. Carbon is usually used as a catalyst support in PEFC, but it is oxidized under high electrical potential conditions. Ti4O7 is expected as a new catalyst support because of its high electrical conductivity and chemical resistivity. Though Ti4O7 as a catalyst support...

2007
Kaifu Huo Yemin Hu Yanwen Ma Yinong Lü Zheng Hu Yi Chen

Single crystalline TiC nanowires have been synthesized through a chloride-assisted carbothermal reduction process using active carbon, TiO2 and NaCl powders as precursors and carbon-coated cobalt or nickel nanoparticles as a catalyst. The products were characterized by x-ray diffraction, electron microscopy, energy-dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy. The TiC nano...

2002

The role of one-dimensional nanostructures has gained immense importance in recent times. These types of nanowires and nanorods are used in probe microscopy, nano electronics, quantum devices and mesoscopic devices. This review compares the various methods used to synthesize such nanowires such as vapor-liquid-solid growth mechanism, oxide assisted nucleation and carbothermal reduction. The dif...

2015
Shuyue Liu Minghao Fang Zhaohui Huang Juntong Huang Haipeng Ji Haitao Liu Yan-gai Liu Xiaowen Wu

The large-scale synthesis of Si3N4 nanobelts from quartz and graphite on a graphite-felt substrate was successfully achieved by catalyst-assisted carbothermal reduction-nitridation. The phase composition, morphology, and microstructure of Si3N4 nanobelts were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, energy-dispersiv...

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