نتایج جستجو برای: carbyne complex

تعداد نتایج: 783940  

2000
P.J.F. Harris

Evaporated carbon support films for transmission electron microscopy often contain carbonaceous contaminants. These include poorly graphitized carbon, fragments of graphite, and fullerene-like structures such as nanotubes and nanoparticles. In some cases, carbyne crystals may also be present. There are many examples in the carbon literature where these contaminants have been mistaken for sample...

2012
Lifeng Wang Ralph T. Yang Chia-Liang Sun

Four types of carbons (activated carbon, Maxsorb superactivated carbon, mesoporous templated carbon CMK-3, and graphene) were investigated as selective sorbents for adsorption of thiophene from its solution in n-octane. Graphene showed clearly the highest sulfur capacity. The relative sulfur capacities correlated well with the relative heats of adsorption. The carbene-type zigzag edge sites and...

Journal: :Journal of the American Chemical Society 2014
Tao Zeng Hui Wang Yunxiang Lu Yaoming Xie Hongyan Wang Henry F Schaefer Nandini Ananth Roald Hoffmann

The challenge motivating this paper is to induce, by chemical substitution, a silylyne, SiR, or a congeneric carbyne, CR, to adopt the high-spin quartet rather than the low-spin doublet as its ground state. The difficulty is seen in the preference for the doublet of the parent SiH (doublet-quartet energy difference ∼39 kcal/mol, favoring the doublet) or CH (∼17 kcal/mol). Strategies for having ...

Journal: :Faraday discussions 2015
Zachary J Lapin Ryan Beams Luiz Gustavo Cançado Lukas Novotny

Nanocarbon materials, including sp(2) hybridized two-dimensional graphene and one-dimensional carbon nanotubes, and sp(1) hybridized one-dimensional carbyne, are being considered for the next generation of integrated optoelectronic devices. The strong electron-phonon coupling present in these nanocarbon materials makes Raman spectroscopy an ideal tool to study and characterize the material and ...

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