We have demonstrated a simple and efficient route for the synthesis of a novel imine based tridentate ligand and its Pd-complex to investigate the C-C cross-coupling reactions, that involve column chromatography purification in only one step. The catalytic activity of the newly synthesized catalyst was studied for the Suzuki, Sonogashira and, Heck cross-coupling reactions under mild conditions....

photodegradation of dicamba, an ionizable herbicide, using tio2 supported on hzsm-11 zeolite was investigated. four photocatalysts with different weight percentages (wt%) of tio2 were evaluated: 3%, 10%, 30% and 50%. the effects of the catalyst concentration, the initial ph value and the repeatability of the photocatalytic activity after multiple cycles of reuse were also evaluated. results sho...

regarding the green chemistry's goals, dicationic magnetic room temperature ionic liquid open up new avenue to introduce an amazing and efficient system for facilitating catalyst recovery in different organic reactions. ability of this dicationic magnetic room temperature ionic liquid catalyst in the one-pot three-components condensation reaction of benzil, aromatic aldehyde, and ammonium aceta...

the kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. the analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.a model based ...

background diatomite coated by nanoparticles of copper and zinc mixed oxides were used to investigate catalytic oxidation of carbon monoxide. objectives aim of this paper was to investigatediatomite performance as a supporting host to confine the cuo and zno nanoparticles and its catalytic activity for carbon monoxide oxidation. materials and methods the prepared catalysts were characterized by...

Abstraet--Jordanian natural kaolin and bentonite show good catalytic activity towards debutylating 2tert-butylphenol, and varying debutylation vs. isomerization selectivity after acid activation. The resulting catalytic activity of these samples is dependent on the acid employed for activation; the samples treated with acetic acid showed relatively low conversions, whereas those treated with hy...

The catalyst activity of fluorite-type oxide, such as ceria and zirconia, for the reduction of sulfur dioxide by carbon monoxide to elemental sulfur can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst with a feed gas of stoichiometri...

A range of catalysts comprising of platinum supported on silica, prepared by an impregnation method, have been studied for the total oxidation of naphthalene, which is a representative Polycyclic Aromatic Hydrocarbon. The influence of platinum loading and calcination temperature on oxidation activity was evaluated. Increasing the platinum loading up to 2.5 wt.% increased the catalyst activity, ...