In situ chemical oxidation is a commonly applied soil and groundwater remediation technology, but can have significant effects on soil properties, which in turn might affect fate and transport of organic contaminants. In this study, it was found that oxidation treatment resulted mainly in breakdown of soil organic matter (SOM) components. Sorption of naphthalene and phenanthrene to the original...

Background: Mature landfill leachate is a complicated mixture which is resistant to biological treatment processes. The treatment of mature landfill leachate by struvite precipitation and Fenton oxidation was the main objective of the current research. Methods: Struvite with the phosphate/ammonia/magnesium molar ratio of 1/1/1.05 was considered during all experiments. Five initial pHs of 3, 4,...

An understanding of bimetallic alloy oxidation is key to the design of hollow-structured binary oxides and the optimization of their catalytic performance. However, one roadblock encountered in studying these binary oxide systems is the difficulty in describing the heterogeneities that occur in both structure and chemistry as a function of reaction coordinate. This is due to the complexity of t...

Oxidation of alloy often involves chemical partition and injection of vacancies. Chemical partition is the consequence of selective oxidation, while injection of vacancies is associated with the differences of diffusivity of cations and anions. It is far from clear as how the injected vacancies behave during oxidation of metal. Using in-situ transmission electron microscopy, we captured unprece...

Formation of leachate poses a problem closely related to the use of landfill sites. Landfill leachate is a wastewater, which as a result of permeation elutes mineral and organic compounds from a bed. Due to its diverse composition, both physical and chemical, it is necessary to purify the leachate before its discharge into drains or a natural receiver. The following article shows that there is ...

It is known that hydrogen peroxide interferes with chemical oxygen demand analysis by consuming oxidation agents such as potassium dichromate, thus leading to overestimation of the chemical oxygen demand measurements. The objective of the study was to investigate the effects of hydrogen peroxide interference and to determine true chemical oxygen demand values on interpreting treatment performan...

The world’s chemical industries face formidable environmental regulatory challenges in treating their wastewater effluents. The present work aims at highlighting the various industrial wastewater treatment technologies currently available including physico-chemical and biological processes as well as constructed wetland and conventional or advanced oxidation processes. Activated carbon prepared...