The orbital g-factor and the spin-orbit splittings of the first excited state of F-centres are measured in NaCl, NaBr, KBr and KF crystals by observing absorption and magnetic circular dichroism at various temperatures and using the moments method. Our experimental results and others are compared with Harker’s theoretical values. LE JOURNAL DE PHYSIQUE TOME 38, OCTOBRE 1977, Classification Phys...

We present an x-ray spectromicroscopic investigation of single-crystalline magnetic FeMn/Co bilayers on Cu 001 , using x-ray magnetic circular dichroism and x-ray magnetic linear dichroism XMLD at the Co and Fe L3 absorption edges in combination with photoelectron emission microscopy. Using the magnetic coupling between the ferromagnetic Co layer and the antiferromagnetic FeMn layer, we are abl...

The effects of YBa2Cu3O72d ~YBCO! cap layers on the magnetic and electronic properties of La0.7Sr0.3MnO3 ~LSMO! underlayers was determined by x-ray magnetic circular dichroism and x-ray absorption spectroscopy techniques. The YBCO caps alter the LSMO in a way that effectively decreases the concentration of La at the LSMO/YBCO interface. © 2000 American Institute of Physics. @S0021-8979~00!62908-0#

Circularly-polarized extreme ultraviolet and X-ray radiation is useful for analysing the structural, electronic and magnetic properties of materials. To date, such radiation has only been available at large-scale X-ray facilities such as synchrotrons. Here, we demonstrate the first bright, phase-matched, extreme ultraviolet circularly-polarized high harmonics source. The harmonics are emitted w...

the L2,3 x-ray fluorescence spectra of magnetized Fe and CO excited by circularly polarized synchrotron radiation exhibit magnetic circular dichroism. The results are compared to the energy resolved spin polarized densities of states given by first-principles calculations.

A novel chiral open-framework fluoroaluminophosphate [C4N3H16][Al6P3O12F6(OH)6] was hydrothermally synthesized using diethylenetriamine as a structure-directing agent. The significant enantiomeric excess of the bulk product was confirmed by the solid state vibrational circular dichroism (VCD) spectrum.

We present measurements of the spin and orbital magnetic moments of Fe3O4 by using SQUID and magnetic circular dichroism in soft x-ray absorption. The measurements show that Fe3O4 has a noninteger spin moment, in contrast to its predicted half-metallic feature. Fe3O4 also exhibits a large unquenched orbital moment. Calculations using the local density approximation including the Hubbard U metho...

The validity of the chromane helicity rule correlating the sense of twist within the dihydropyran ring with the CD sign of the (1)Lb band observed at ca. 290 nm in their electronic circular dichroism (ECD) spectra is examined using a set of natural (S)-trolox derivatives. To investigate both the scope and the limitations of the rule a combination of ECD spectroscopy, especially the temperature ...

We have investigated the individual magnetic moments of Ni, Mn and Tb atoms in the intermetallic compound TbNi2Mn in the Laves phase (magnetic phase transition temperature TC ∼131 K) by X-ray magnetic circular dichroism (XMCD) studies at 300 K, 80 K and 20 K. Analyses of the experimental results reveal that Ni atoms at 20 K in an applied magnetic field of 1 T carry an intrinsic magnetic moment ...