نتایج جستجو برای: classical transition state
تعداد نتایج: 1232531 فیلتر نتایج به سال:
Following an experimental observation, a recent simulation has shown that efficient population transfer can be achieved through adiabatic chirping of a microwave pulse through a 10-photon resonance connecting two Rydberg states with n = 72, = 1 and n ∼ 82. These simulations have revealed that this population transfer is essentially a classical transition caused by separatrix crossing in the cla...
The properties of a frustrated quantum antiferromagnet are interesting topics in condensed matter theory. Among the quantum antiferromagnets, Cs2CuC14 gains attention as one of the candidates for materials with ground state spin liquid phase. The recent experimental results show that there exist several ground state phases in the presence of magnetic field which cannot be explained with classic...
We perform quantum mechanically exact calculations of resonances in the spectrum of the hydrogen atom in crossed external fields and establish a close connection between the classical transition state in phase space and features in the quantum spectrum. By varying the external field strengths, structures are revealed which are surprisingly similar to the quantized energy levels of the classical...
We develop a novel approach to phase transitions in quantum spin models based on a relation to their classical counterparts. Explicitly, we show that whenever chessboard estimates can be used to prove a phase transition in the classical model, the corresponding quantum model will have a similar phase transition, provided the inverse temperature β and the magnitude of the quantum spins S satisfy...
We develop a novel approach to phase transitions in quantum spin models based on a relation to the corresponding classical spin systems. Explicitly, we show that whenever chessboard estimates can be used to prove a phase transition in the classical model, the corresponding quantum model will have a similar phase transition, provided the inverse temperature β and the magnitude of the quantum spi...
Transition-path theory is a theoretical framework for describing rare events in complex systems. It can also be used as a starting point for developing efficient numerical algorithms for analyzing such rare events. Here we review the basic components of transition-path theory and path-finding algorithms. We also discuss connections with the classical transition-state theory.
The interplay of charge, spin and lattice degrees of freedom is studied for quasi-one-dimensional electron and spin systems coupled to quantum phonons. Special emphasis is put on the influence of the lattice dynamics on the Peierls transition. Using exact diagonalization techniques the ground-state and spectral properties of the Holstein model of spinless fermions and of a frustrated Heisenberg...
The ground state and the finite temperature phase diagrams with respect to magnetic configurations are studied systematically for thin magnetic films in terms of a classical Heisenberg model including magnetic dipole-dipole interaction and uniaxial anisotropy. Simple relations are derived for the occurrence of the various phase boundaries between the different regions of the magnetic orientatio...
objective(s) physiological changes in the body may be utilized as potential triggers for controlled drug delivery. based on these mechanisms, stimulus-responsive drug delivery has been developed. materials and methods in this study, a kind of poly (n-isopropylacrylamide-acrylamide) membrane was prepared by radical copolymerization. changes in swelling ratios and diameters of the membrane were i...
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