Atmospheric CO2 concentrations continue to rise rapidly in response to increased combustion of fossil fuels, contributing to global climate change. In order to mitigate the effects of global warming, development of new materials for cost-effective and energy-efficient CO2 capture is critically important. Graphene-based porous materials are an emerging class of solid adsorbents for selectively r...

Future use of coal for power generation in the US depends on technologies being made available to capture and store CO2 emissions from power plants. A key candidate CO2 capture technology is oxy-firing of coal. Application of oxy-firing to existing power plants presents unquantified challenges as the characteristics of oxy-firing compared to airfiring have not been fully determined. This presen...

The Cryogenic Carbon CaptureTM (CCC) process is a retrofit, post-combustion technology that desublimates CO2 in the flue gas, separates the resulting solid from the remaining light gases, pressurizes the solid CO2, melts the CO2 and warms the light gas, and completes the CO2 pressurization with liquid CO2. This skid-scale CCC system has demonstrated successful carbon capture of 90–99% from simu...

Chemical-Looping Combustion (CLC) is an emerging technology for CO2 capture because separation of this gas from the other flue gas components is inherent to the process and thus no energy is expended for the separation. Natural or refinery gas can be used as gaseous fuels and they may contain different amounts of light hydrocarbons. This paper presents the combustion results obtained with a Cu-...

Introduction of closed cycle gas turbines with their capability of retaining combustion generated CO2 can offer a valuable contribution to the Kyoto goal and to future power generation. Therefore research and development at Graz University of Technology since the 90's has lead to the Graz Cycle, a zero emission power cycle of highest efficiency. It burns fossil fuels with pure oxygen which enab...

The projections of energy related carbon dioxide (CO2) emissions in the Special Report on Emission Scenarios (SRES) of the Intergovernmental Panel on Climate Change (IPCC) serve as point of departure for an assessment of plausible ranges of CO2 emissions that could be avoided through CO2 capture and storage measures. Scenario and time dependent, sector and fuel specific capture factors are deve...

Flue gas from a plant using fossil fuels contains CO2. Thus power/process plants using fossil fuels contribute to climate change if CO2 in flue gas is not captured. The process of CO2 capture from flue gas is called „postcombustion‟ CO2 capture. Existing plants may be retrofitted with this process to minimize CO2 emission. Amine solutions are mostly used for this process to scrub the flue gas. ...